Zeolite with tunable intracrystal mesoporosity synthesized with carbon aerogel as a secondary template

Yunming Fang, Haoquan Hu, Guohua Chen

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

22 Citations (Scopus)

Abstract

In this paper, carbon aerogel was investigated as a potential template for generating size controllable intracrystal mesopore system in zeolite. For this purpose zeolite samples were synthesized with carbon aerogels having different structural parameters as secondary template, and characterized with XRD, FT-IR, SEM, TEM as well as low-temperature nitrogen adsorption. Results indicated that the carbon aerogel synthesized by simple ambient drying method can be used for generating additional intracrystal mesopore channel in zeolite without special control on the crystallization conditions. The pore size of the additional intracrystal mesopore system in zeolite can be controlled over a wide range by simply changing the catalyst concentration during sol-gel reaction of resorcinol and formaldehyde, the initial step of carbon aerogel synthesis. © 2008 Elsevier Inc. All rights reserved.
Original languageEnglish
Pages (from-to)481-489
JournalMicroporous and Mesoporous Materials
Volume113
Issue number1-3
DOIs
Publication statusPublished - 1 Aug 2008
Externally publishedYes

Bibliographical note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Research Keywords

  • Carbon aerogel
  • Intracrystal mesoporosity
  • Nanocasting
  • Secondary template
  • Zeolite

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