Zeolite-PAN/PVDF composite nanofiber membranes for highly efficient and selective removal of cationic dyes from wastewater

Muhamad F. Arif; Sephia Amanda Muhtar; Cindy Siburian; Kurniawan Deny Pratama Marpaung; Nursidik Yulianto; Fatwa F. Abdi; Tarmizi Taher; Hutomo Suryo Wasisto; Aditya Rianjanu

doi:10.1016/j.cscee.2024.100806

Zeolite-PAN/PVDF composite nanofiber membranes for highly efficient and selective removal of cationic dyes from wastewater

Muhamad F. Arif^*
, Sephia Amanda Muhtar
, Cindy Siburian
, Kurniawan Deny Pratama Marpaung
, Nursidik Yulianto
, Fatwa F. Abdi
, Tarmizi Taher^*
, Hutomo Suryo Wasisto^*
, Aditya Rianjanu^*

^*Corresponding author for this work

School of Energy and Environment

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

25 Citations (Scopus)

123 Downloads (CityUHK Scholars)

Abstract

This study presents a novel composite nanofiber membrane combining polyacrylonitrile/polyvinylidene fluoride (PAN/PVDF) electrospun nanofibers with locally sourced zeolite from Sumatera, Indonesia, for pollutant dye filtration. The Ze-PAN/PVDF composite nanofiber membrane has 100% methylene blue dye rejection even after five filtration cycles with a permeation flux of 185 L m⁻² h⁻¹ bar⁻¹. The membrane is highly selective, with 100% dye filtration efficiency for cationic dyes (i.e., methylene blue and crystal violet) vs. 78% and 1% for anionic dyes (i.e., Congo red and methyl orange, respectively). For the cationic dyes, the dye filtration mechanism is mainly governed by electrostatic attraction, while the size exclusion mechanism becomes more dominant for the anionic dyes. Overall, these results demonstrate the potential use of Ze-PAN/PVDF composite nanofiber membrane in wastewater treatment applications. © 2024 The Authors

Original language	English
Article number	100806
Journal	Case Studies in Chemical and Environmental Engineering
Volume	10
Online published	17 Jun 2024
DOIs	https://doi.org/10.1016/j.cscee.2024.100806
Publication status	Published - Dec 2024

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 6 Clean Water and Sanitation

Research Keywords

Composite nanofiber
Dye filtration
Membrane
Wastewater treatment
Zeolite clinoptilolite

Publisher's Copyright Statement

This full text is made available under CC-BY-NC 4.0. https://creativecommons.org/licenses/by-nc/4.0/

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10.1016/j.cscee.2024.100806

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Arif, M. F., Muhtar, S. A., Siburian, C., Marpaung, K. D. P., Yulianto, N., Abdi, F. F., Taher, T., Wasisto, H. S., & Rianjanu, A. (2024). Zeolite-PAN/PVDF composite nanofiber membranes for highly efficient and selective removal of cationic dyes from wastewater. Case Studies in Chemical and Environmental Engineering, 10, Article 100806. https://doi.org/10.1016/j.cscee.2024.100806

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title = "Zeolite-PAN/PVDF composite nanofiber membranes for highly efficient and selective removal of cationic dyes from wastewater",

abstract = "This study presents a novel composite nanofiber membrane combining polyacrylonitrile/polyvinylidene fluoride (PAN/PVDF) electrospun nanofibers with locally sourced zeolite from Sumatera, Indonesia, for pollutant dye filtration. The Ze-PAN/PVDF composite nanofiber membrane has 100\% methylene blue dye rejection even after five filtration cycles with a permeation flux of 185 L m−2 h−1 bar−1. The membrane is highly selective, with 100\% dye filtration efficiency for cationic dyes (i.e., methylene blue and crystal violet) vs. 78\% and 1\% for anionic dyes (i.e., Congo red and methyl orange, respectively). For the cationic dyes, the dye filtration mechanism is mainly governed by electrostatic attraction, while the size exclusion mechanism becomes more dominant for the anionic dyes. Overall, these results demonstrate the potential use of Ze-PAN/PVDF composite nanofiber membrane in wastewater treatment applications. {\textcopyright} 2024 The Authors",

keywords = "Composite nanofiber, Dye filtration, Membrane, Wastewater treatment, Zeolite clinoptilolite",

author = "Arif, \{Muhamad F.\} and Muhtar, \{Sephia Amanda\} and Cindy Siburian and Marpaung, \{Kurniawan Deny Pratama\} and Nursidik Yulianto and Abdi, \{Fatwa F.\} and Tarmizi Taher and Wasisto, \{Hutomo Suryo\} and Aditya Rianjanu",

year = "2024",

month = dec,

doi = "10.1016/j.cscee.2024.100806",

language = "English",

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Zeolite-PAN/PVDF composite nanofiber membranes for highly efficient and selective removal of cationic dyes from wastewater. / Arif, Muhamad F.; Muhtar, Sephia Amanda; Siburian, Cindy et al.
In: Case Studies in Chemical and Environmental Engineering, Vol. 10, 100806, 12.2024.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Zeolite-PAN/PVDF composite nanofiber membranes for highly efficient and selective removal of cationic dyes from wastewater

AU - Arif, Muhamad F.

AU - Muhtar, Sephia Amanda

AU - Siburian, Cindy

AU - Marpaung, Kurniawan Deny Pratama

AU - Yulianto, Nursidik

AU - Abdi, Fatwa F.

AU - Taher, Tarmizi

AU - Wasisto, Hutomo Suryo

AU - Rianjanu, Aditya

PY - 2024/12

Y1 - 2024/12

N2 - This study presents a novel composite nanofiber membrane combining polyacrylonitrile/polyvinylidene fluoride (PAN/PVDF) electrospun nanofibers with locally sourced zeolite from Sumatera, Indonesia, for pollutant dye filtration. The Ze-PAN/PVDF composite nanofiber membrane has 100% methylene blue dye rejection even after five filtration cycles with a permeation flux of 185 L m−2 h−1 bar−1. The membrane is highly selective, with 100% dye filtration efficiency for cationic dyes (i.e., methylene blue and crystal violet) vs. 78% and 1% for anionic dyes (i.e., Congo red and methyl orange, respectively). For the cationic dyes, the dye filtration mechanism is mainly governed by electrostatic attraction, while the size exclusion mechanism becomes more dominant for the anionic dyes. Overall, these results demonstrate the potential use of Ze-PAN/PVDF composite nanofiber membrane in wastewater treatment applications. © 2024 The Authors

AB - This study presents a novel composite nanofiber membrane combining polyacrylonitrile/polyvinylidene fluoride (PAN/PVDF) electrospun nanofibers with locally sourced zeolite from Sumatera, Indonesia, for pollutant dye filtration. The Ze-PAN/PVDF composite nanofiber membrane has 100% methylene blue dye rejection even after five filtration cycles with a permeation flux of 185 L m−2 h−1 bar−1. The membrane is highly selective, with 100% dye filtration efficiency for cationic dyes (i.e., methylene blue and crystal violet) vs. 78% and 1% for anionic dyes (i.e., Congo red and methyl orange, respectively). For the cationic dyes, the dye filtration mechanism is mainly governed by electrostatic attraction, while the size exclusion mechanism becomes more dominant for the anionic dyes. Overall, these results demonstrate the potential use of Ze-PAN/PVDF composite nanofiber membrane in wastewater treatment applications. © 2024 The Authors

KW - Composite nanofiber

KW - Dye filtration

KW - Membrane

KW - Wastewater treatment

KW - Zeolite clinoptilolite

UR - https://www.scopus.com/pages/publications/85196298654

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85196298654&origin=recordpage

U2 - 10.1016/j.cscee.2024.100806

DO - 10.1016/j.cscee.2024.100806

M3 - RGC 21 - Publication in refereed journal

SN - 2666-0164

VL - 10

JO - Case Studies in Chemical and Environmental Engineering

JF - Case Studies in Chemical and Environmental Engineering

M1 - 100806

ER -

Zeolite-PAN/PVDF composite nanofiber membranes for highly efficient and selective removal of cationic dyes from wastewater

Abstract

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Research Keywords

Publisher's Copyright Statement

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