Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

12 Scopus Citations
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Author(s)

  • Jing Xiang
  • Min Peng
  • Yi Pan
  • Li-Juan Luo
  • Shun-Cheung Cheng
  • Xin-Xin Jin
  • Shek-Man Yiu
  • Wai-Lun Man
  • Tai-Chu Lau

Related Research Unit(s)

Detail(s)

Original languageEnglish
Pages (from-to)14494-14498
Journal / PublicationChemical Science
Volume12
Issue number43
Online published9 Oct 2021
Publication statusPublished - 21 Nov 2021

Link(s)

Abstract

N-Dealkylation of amines by metal oxo intermediates (M=O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.

Research Area(s)

  • BOND-DISSOCIATION ENERGIES, REACTIVITY, NONHEME, CYTOCHROME-P450, AZIRIDINATION, ACTIVATION, DINITROGEN, AMMONIA, ACIDITY, AMINES

Citation Format(s)

Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex. / Xiang, Jing; Peng, Min; Pan, Yi et al.
In: Chemical Science, Vol. 12, No. 43, 21.11.2021, p. 14494-14498.

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

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