Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

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Author(s)

  • Jing Xiang
  • Min Peng
  • Yi Pan
  • Li-Juan Luo
  • Shun-Cheung Cheng
  • Xin-Xin Jin
  • Shek-Man Yiu
  • Wai-Lun Man
  • Tai-Chu Lau

Related Research Unit(s)

Detail(s)

Original languageEnglish
Pages (from-to)14494-14498
Journal / PublicationChemical Science
Volume12
Issue number43
Online published9 Oct 2021
Publication statusPublished - 21 Nov 2021

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Publisher's Copyright Statement
  • This full text is made available under CC-BY-NC 3.0. https://creativecommons.org/licenses/by-nc/3.0/
Link to Scopus https://www.scopus.com/record/display.uri?eid=2-s2.0-85118953330&origin=recordpage
Permanent Link https://scholars.cityu.edu.hk/en/publications/publication(ef478cac-babf-497d-a6bc-c07a6d0970f1).html

Abstract

N-Dealkylation of amines by metal oxo intermediates (M=O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.

Research Area(s)

  • BOND-DISSOCIATION ENERGIES, REACTIVITY, NONHEME, CYTOCHROME-P450, AZIRIDINATION, ACTIVATION, DINITROGEN, AMMONIA, ACIDITY, AMINES

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Publication fingerprints text

100
Luminiscence Type Chemistry
100
Osmium Chemistry
100
Alkylamine Chemistry
100
Dealkylation Chemistry
100
Visible Spectrum Chemistry
50
DNA Repair Material Science
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Citation Format(s)

[ RIS ] [ BibTeX ]
Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex. / Xiang, Jing; Peng, Min; Pan, Yi et al.
In: Chemical Science, Vol. 12, No. 43, 21.11.2021, p. 14494-14498.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

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