TY - JOUR
T1 - Vinylene-Inserted Asymmetric Polymer Acceptor with Absorption Approaching 1000 nm for Versatile Applications in All-Polymer Solar Cells and Photomultiplication-Type Polymeric Photodetectors
AU - Fan, Qunping
AU - Fu, Huiting
AU - Liu, Ming
AU - Oh, Jiyeon
AU - Ma, Xiaoling
AU - Lin, Francis R.
AU - Yang, Changduk
AU - Zhang, Fujun
AU - Jen, Alex K-Y
PY - 2022/6/15
Y1 - 2022/6/15
N2 - The emerging polymerized small-molecule acceptors (PSMAs) with near-infrared (NIR) absorption have not only significantly boosted the power conversion efficiencies (PCEs) of all-polymer solar cells (all-PSCs) but have also exhibited great potential for sensitive NIR polymeric photodetectors (PPDs). However, there is no report regarding PSMAs with photo-response that can approach 1000 nm, which is an important criterion for applications in NIR-responsive all-PSCs and PPDs. Herein, by unidirectionally inserting vinylene segments into a selenophene-rich polymer backbone to improve the electron-donating strength and quinoidal character, an asymmetric PSMA, namely, PY3Se-1V, was developed, which showed an extensively red-shifted absorption approaching 1000 nm. The PBDB-T:PY3Se-1V-based binary all-PSCs achieve a decent PCE of 13.2% and a record-high photocurrent density of 25.9 mA cm-2 due to the significantly broadened photo-response and efficient photon-to-electron conversion. More encouragingly, narrowband photomultiplication (PM)-type PPDs based on poly(3-hexylthiophene-2,5-diyl) (P3HT):PY3Se-1V were developed, delivering an exceptionally high external quantum efficiency of 3680% and a responsivity of 28 A W-1 at an NIR peak of 960 nm under -50 V bias, which is reported for the first time in PM-type PPDs with a response approaching 1000 nm.
AB - The emerging polymerized small-molecule acceptors (PSMAs) with near-infrared (NIR) absorption have not only significantly boosted the power conversion efficiencies (PCEs) of all-polymer solar cells (all-PSCs) but have also exhibited great potential for sensitive NIR polymeric photodetectors (PPDs). However, there is no report regarding PSMAs with photo-response that can approach 1000 nm, which is an important criterion for applications in NIR-responsive all-PSCs and PPDs. Herein, by unidirectionally inserting vinylene segments into a selenophene-rich polymer backbone to improve the electron-donating strength and quinoidal character, an asymmetric PSMA, namely, PY3Se-1V, was developed, which showed an extensively red-shifted absorption approaching 1000 nm. The PBDB-T:PY3Se-1V-based binary all-PSCs achieve a decent PCE of 13.2% and a record-high photocurrent density of 25.9 mA cm-2 due to the significantly broadened photo-response and efficient photon-to-electron conversion. More encouragingly, narrowband photomultiplication (PM)-type PPDs based on poly(3-hexylthiophene-2,5-diyl) (P3HT):PY3Se-1V were developed, delivering an exceptionally high external quantum efficiency of 3680% and a responsivity of 28 A W-1 at an NIR peak of 960 nm under -50 V bias, which is reported for the first time in PM-type PPDs with a response approaching 1000 nm.
KW - all-polymer solar cells
KW - asymmetric polymer acceptors
KW - near-infrared absorption
KW - photomultiplication-type polymeric photodetectors
KW - vinylene
KW - 17-PERCENT EFFICIENCY
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UR - http://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=LinksAMR&SrcApp=PARTNER_APP&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000812472600001
UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85132127428&origin=recordpage
U2 - 10.1021/acsami.2c02485
DO - 10.1021/acsami.2c02485
M3 - RGC 21 - Publication in refereed journal
SN - 1944-8244
VL - 14
SP - 26970
EP - 26977
JO - ACS Applied Materials & Interfaces
JF - ACS Applied Materials & Interfaces
IS - 23
ER -
SDG 7 Affordable and Clean Energy