Vacuum ultraviolet pulsed field ionization study of ND3: Accurate thermochemistry for the ND2-ND2+ and ND3-ND3+ system

X.-M. Qian; K.-C. Lau; G. Z. He; C. Y. Ng; M. Hochlaf

doi:10.1063/1.1691406

Vacuum ultraviolet pulsed field ionization study of ND₃: Accurate thermochemistry for the ND₂-ND₂⁺ and ND₃-ND₃⁺ system

X.-M. Qian, K.-C. Lau, G. Z. He, C. Y. Ng^*, M. Hochlaf

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

11 Citations (Scopus)

Abstract

The pulse field ionization (PFI)-photoelectron (PFI-PE) vibrational bands for ND₃were recorded using high resolution VUV synchrotron radiation. The breakdown curves of ND₂⁺ and ND₃⁺ measured near the first dissociation threshold helped in the determination of the O K appearance energy (AE) of ND₂⁺. The AE value in turn made possible the determination of D₀(D-ND ₂⁺), and the ionization energy (IE) of ND₂ through appropriate thermochemical cycles.

Original language	English
Pages (from-to)	8476-8484
Journal	Journal of Chemical Physics
Volume	120
Issue number	18
DOIs	https://doi.org/10.1063/1.1691406
Publication status	Published - 8 May 2004
Externally published	Yes

Access Output

10.1063/1.1691406

Other Access Options

Check CityUHK Library

Permanent Link

Right click to copy link

Cite this

@article{cf131931d92a4d6584fcd74618745d75,

title = "Vacuum ultraviolet pulsed field ionization study of ND3: Accurate thermochemistry for the ND2-ND2+ and ND3-ND3+ system",

abstract = "The pulse field ionization (PFI)-photoelectron (PFI-PE) vibrational bands for ND3 were recorded using high resolution VUV synchrotron radiation. The breakdown curves of ND2+ and ND3+ measured near the first dissociation threshold helped in the determination of the O K appearance energy (AE) of ND2+. The AE value in turn made possible the determination of D0(D-ND 2+), and the ionization energy (IE) of ND2 through appropriate thermochemical cycles.",

author = "X.-M. Qian and K.-C. Lau and He, {G. Z.} and Ng, {C. Y.} and M. Hochlaf",

year = "2004",

month = may,

day = "8",

doi = "10.1063/1.1691406",

language = "English",

volume = "120",

pages = "8476--8484",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "18",

}

TY - JOUR

T1 - Vacuum ultraviolet pulsed field ionization study of ND3

T2 - Accurate thermochemistry for the ND2-ND2+ and ND3-ND3+ system

AU - Qian, X.-M.

AU - Lau, K.-C.

AU - He, G. Z.

AU - Ng, C. Y.

AU - Hochlaf, M.

PY - 2004/5/8

Y1 - 2004/5/8

N2 - The pulse field ionization (PFI)-photoelectron (PFI-PE) vibrational bands for ND3 were recorded using high resolution VUV synchrotron radiation. The breakdown curves of ND2+ and ND3+ measured near the first dissociation threshold helped in the determination of the O K appearance energy (AE) of ND2+. The AE value in turn made possible the determination of D0(D-ND 2+), and the ionization energy (IE) of ND2 through appropriate thermochemical cycles.

AB - The pulse field ionization (PFI)-photoelectron (PFI-PE) vibrational bands for ND3 were recorded using high resolution VUV synchrotron radiation. The breakdown curves of ND2+ and ND3+ measured near the first dissociation threshold helped in the determination of the O K appearance energy (AE) of ND2+. The AE value in turn made possible the determination of D0(D-ND 2+), and the ionization energy (IE) of ND2 through appropriate thermochemical cycles.

UR - http://www.scopus.com/inward/record.url?scp=2542431247&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-2542431247&origin=recordpage

U2 - 10.1063/1.1691406

DO - 10.1063/1.1691406

M3 - RGC 21 - Publication in refereed journal

SN - 0021-9606

VL - 120

SP - 8476

EP - 8484

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 18

ER -