Vacuum ultraviolet pulsed field ionization study of ND3 : Accurate thermochemistry for the ND2-ND2+ and ND3-ND3+ system

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

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Author(s)

  • X.-M. Qian
  • K.-C. Lau
  • G. Z. He
  • C. Y. Ng
  • M. Hochlaf

Detail(s)

Original languageEnglish
Pages (from-to)8476-8484
Journal / PublicationJournal of Chemical Physics
Volume120
Issue number18
Publication statusPublished - 8 May 2004
Externally publishedYes

Abstract

The pulse field ionization (PFI)-photoelectron (PFI-PE) vibrational bands for NDwere recorded using high resolution VUV synchrotron radiation. The breakdown curves of ND2+ and ND3+ measured near the first dissociation threshold helped in the determination of the O K appearance energy (AE) of ND2+. The AE value in turn made possible the determination of D0(D-ND 2+), and the ionization energy (IE) of ND2 through appropriate thermochemical cycles.