Unraveling the Role of Aromatic Ring Size in Tuning the Electrochemical Performance of Small-Molecule Imide Cathodes for Lithium-Ion Batteries

Organic electrode materials have the typical advantages of flexibility, low cost, abundant resources, and recyclability. However, it is challenging to simultaneously optimize the specific capacity, rate capability, and cycling stability. Radicals are inevitable intermediates that critically determine the redox activity and stability during the electrochemical reaction of organic electrodes. Herein, we select a series of aromatic imides, including pyromellitic diimide (PMDI), 1,4,5,8-naphthalenediimide (NDI), and 3,4,9,10-perylenetetracarboxylicdiimide (PTCDI), which contain different extending π-conjugated aromatic rings, to study the relationship between their electrochemical performance and the size of the aromatic ring. The results show that regulating the aromatic ring size of imide molecules could finely tune the energies of the lowest unoccupied molecular orbital (LUMO), thus optimizing the redox potential. The rate performance of PMDI, NDI, and PTCDI increases with the aromatic ring size, which is consistent with the decrease in the LUMO−HOMO gap of these imide molecules. DFT calculations and experiments reveal that the redox of imide radicals dominates the charge/discharge processes. Also, extending the aromatic rings could more effectively disperse the spin electron density and improve the stability of imide radicals, contributing to the enhanced cycling stability of these imide electrodes. Hence, aromatic ring size regulation is a simple and novel approach to simultaneously enhance the capacity, rate capability, and cycling stability of organic electrodes for high-performance lithium-ion batteries.