Unraveling structural, electronic, and magnetic ambiguities in Pb_1-δCrO₃ with an insulating charge-transfer band structure

As a recently identified Mott system, PbCrO₃ remains largely unexplored, especially for its band structure, leading to many contentious issues on its structural, electronic, and magnetic properties. Here we present a comprehensive study of two different Pb_1-δCrO₃ (δ = 0 and 0.15) samples involving atomic deficiency prepared under pressure. By means of state-of-the-art diffraction techniques, the crystal structure of PbCrO₃ is definitively determined to adopt the pristine Pm3¯m symmetry, rather than other previously misassigned structures of M2-Pm3¯m and Pmnm. The two materials exhibit a similar charge-transfer-type insulating band structure, and the charge-transfer effect splits both Cr 2p and Pb 4f orbitals, rationalizing doublet splitting of the associated spectral lines. Nearly identical nominal cationic valence states of Cr⁴⁺ and Pb²⁺ are identified for this oxide system, hence calling into question the validity of recently proposed charge disproportionation mechanisms. In addition, Pb_0.85CrO₃ exhibits an anomalously higher Néel temperature of ∼240 K than that of PbCrO₃ (i.e., ∼200 K), likely due to the deficiency-induced enhancements of Cr3d-O2p orbital overlap and magnetic exchange. These findings provide much solid evidence to look into the fundamental properties of this important material system. © 2025 American Physical Society.