Ultralarge and Thermally Stable Electro-optic Activities from Diels–Alder Crosslinkable Polymers Containing Binary Chromophore Systems

Tae-Dong Kim; Jingdong Luo; Jae-Won Ka; Steven Hau; Yanqing Tian; Zhengwei Shi; Neil M. Tucker; Sei-Hum Jang; Jae-Wook Kang; Alex K.-Y. Jen

doi:10.1002/adma.200601582

Ultralarge and Thermally Stable Electro-optic Activities from Diels–Alder Crosslinkable Polymers Containing Binary Chromophore Systems

Tae-Dong Kim, Jingdong Luo, Jae-Won Ka, Steven Hau, Yanqing Tian, Zhengwei Shi, Neil M. Tucker, Sei-Hum Jang, Jae-Wook Kang, Alex K.-Y. Jen^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

116 Citations (Scopus)

Abstract

The dispersion of an efficient secondary chromophore into in situ crosslinked nonlinear optical polymer networks is described. The secondary chromophore leads to both enhanced electro‐optical (EO) activity (> 260 pm V^–1 at 1.31 μm) and alignment stability at 85 °C. Analysis of the EO properties shows exceptional poling efficiency of these binary systems at high chromophore loading levels, in contrast to experimental results obtained from single‐chromophore polymers.

Original language	English
Pages (from-to)	3038-3042
Journal	Advanced Materials
Volume	18
Issue number	22
Online published	27 Oct 2006
DOIs	https://doi.org/10.1002/adma.200601582
Publication status	Published - Nov 2006
Externally published	Yes

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@article{edc6b3a6e0db4d63a9d98918589c9ea2,

title = "Ultralarge and Thermally Stable Electro-optic Activities from Diels–Alder Crosslinkable Polymers Containing Binary Chromophore Systems",

abstract = "The dispersion of an efficient secondary chromophore into in situ crosslinked nonlinear optical polymer networks is described. The secondary chromophore leads to both enhanced electro‐optical (EO) activity (> 260 pm V–1 at 1.31 μm) and alignment stability at 85 °C. Analysis of the EO properties shows exceptional poling efficiency of these binary systems at high chromophore loading levels, in contrast to experimental results obtained from single‐chromophore polymers.",

author = "Tae-Dong Kim and Jingdong Luo and Jae-Won Ka and Steven Hau and Yanqing Tian and Zhengwei Shi and Tucker, {Neil M.} and Sei-Hum Jang and Jae-Wook Kang and Jen, {Alex K.-Y.}",

year = "2006",

month = nov,

doi = "10.1002/adma.200601582",

language = "English",

volume = "18",

pages = "3038--3042",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-Blackwell",

number = "22",

}

TY - JOUR

T1 - Ultralarge and Thermally Stable Electro-optic Activities from Diels–Alder Crosslinkable Polymers Containing Binary Chromophore Systems

AU - Kim, Tae-Dong

AU - Luo, Jingdong

AU - Ka, Jae-Won

AU - Hau, Steven

AU - Tian, Yanqing

AU - Shi, Zhengwei

AU - Tucker, Neil M.

AU - Jang, Sei-Hum

AU - Kang, Jae-Wook

AU - Jen, Alex K.-Y.

PY - 2006/11

Y1 - 2006/11

N2 - The dispersion of an efficient secondary chromophore into in situ crosslinked nonlinear optical polymer networks is described. The secondary chromophore leads to both enhanced electro‐optical (EO) activity (> 260 pm V–1 at 1.31 μm) and alignment stability at 85 °C. Analysis of the EO properties shows exceptional poling efficiency of these binary systems at high chromophore loading levels, in contrast to experimental results obtained from single‐chromophore polymers.

AB - The dispersion of an efficient secondary chromophore into in situ crosslinked nonlinear optical polymer networks is described. The secondary chromophore leads to both enhanced electro‐optical (EO) activity (> 260 pm V–1 at 1.31 μm) and alignment stability at 85 °C. Analysis of the EO properties shows exceptional poling efficiency of these binary systems at high chromophore loading levels, in contrast to experimental results obtained from single‐chromophore polymers.

UR - http://www.scopus.com/inward/record.url?scp=33845188700&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-33845188700&origin=recordpage

U2 - 10.1002/adma.200601582

DO - 10.1002/adma.200601582

M3 - RGC 21 - Publication in refereed journal

SN - 0935-9648

VL - 18

SP - 3038

EP - 3042

JO - Advanced Materials

JF - Advanced Materials

IS - 22

ER -

Ultralarge and Thermally Stable Electro-optic Activities from Diels–Alder Crosslinkable Polymers Containing Binary Chromophore Systems

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