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Two-photon polymerized structural color microblocks with pH response for information encryption

  • Yuzhao Zhang
  • , Haibo Yu
  • , Jianchen Zheng
  • , Jingang Wang
  • , Lianqing Liu
  • , Wen Jung Li

Research output: Chapters, Conference Papers, Creative and Literary WorksRGC 32 - Refereed conference paper (with host publication)peer-review

Abstract

"Structural coloring" is a stable and environmentally friendly way to present color and has a wide range of applications in areas such as information encryption, optical anti-counterfeiting measures, and sensors. In this study, we create color changeable microblocks with pH response by two-photon polymerization. We printed three-dimensional microblocks similar to woodpiles using layer-by-layer line processing and created microblocks containing different colors by varying the processing parameters. These microblocks are pH-responsive and can shrink and swell rapidly in response to changes in the acidity or alkalinity of the solution to which they are exposed. These changes allow the microblocks to undergo reversible color changes. Furthermore, the pH-responsive function enables the encryption of patterned information that is visible under acidic conditions but rapidly becomes invisible under alkaline conditions. The excellent responsiveness and reversibility of this micro-structured surface has potential applications in anti-counterfeit information hiding, environmental sensing, and tunable optical devices.

© 2023 IEEE
Original languageEnglish
Title of host publication2023 IEEE 23rd International Conference on Nanotechnology (NANO)
PublisherIEEE
ISBN (Electronic)979-8-3503-3346-6
DOIs
Publication statusPublished - 2023

Funding

The authors wish to acknowledge the National Natural Science Foundation of China (Grant Nos. 61927085 and 61973298) and Hong Kong Research Grants Council (GRF Project Number 11216120).

RGC Funding Information

  • RGC-funded

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