Two-Photon Absorption of Butterfly-Shaped Carbonyl-Bridged Twistarene

Xianglong Wu; Zhihui Chen; Wangqiao Chen; Fei Yu; Guofu Zhou; Qinghua Xu; Qichun Zhang

doi:10.1002/ajoc.202000101

Two-Photon Absorption of Butterfly-Shaped Carbonyl-Bridged Twistarene

Xianglong Wu
, Zhihui Chen
, Wangqiao Chen
, Fei Yu
, Guofu Zhou^*
, Qinghua Xu^*
, Qichun Zhang^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

2 Citations (Scopus)

Abstract

The single crystals of a butterfly-shaped carbonyl-bridged twistarene 3 were obtained by slow diffusion of methanol into its chloroform solution. The single-crystal structure analysis indicated that 3 crystallized in a triclinic space group (P-1). The two-photon absorption (TPA) and nonlinear optical properties of single crystal of 3 were investigated in the range of 400 nm ∼650 nm. This is the first example of the TPA study based on single crystals made from the carbonyl-bridged twistarene. The corresponding TPA cross-section was found to be 3.69 GM at 800 nm.

Original language	English
Pages (from-to)	579-583
Journal	Asian Journal of Organic Chemistry
Volume	9
Issue number	4
Online published	26 Feb 2020
DOIs	https://doi.org/10.1002/ajoc.202000101
Publication status	Published - Apr 2020
Externally published	Yes

Research Keywords

Computational chemistry
Crystal structure
Fluorescence spectroscopy
Twistarene
Two-photon absorption

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10.1002/ajoc.202000101

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title = "Two-Photon Absorption of Butterfly-Shaped Carbonyl-Bridged Twistarene",

abstract = "The single crystals of a butterfly-shaped carbonyl-bridged twistarene 3 were obtained by slow diffusion of methanol into its chloroform solution. The single-crystal structure analysis indicated that 3 crystallized in a triclinic space group (P-1). The two-photon absorption (TPA) and nonlinear optical properties of single crystal of 3 were investigated in the range of 400 nm ∼650 nm. This is the first example of the TPA study based on single crystals made from the carbonyl-bridged twistarene. The corresponding TPA cross-section was found to be 3.69 GM at 800 nm.",

keywords = "Computational chemistry, Crystal structure, Fluorescence spectroscopy, Twistarene, Two-photon absorption, Computational chemistry, Crystal structure, Fluorescence spectroscopy, Twistarene, Two-photon absorption, Computational chemistry, Crystal structure, Fluorescence spectroscopy, Twistarene, Two-photon absorption",

author = "Xianglong Wu and Zhihui Chen and Wangqiao Chen and Fei Yu and Guofu Zhou and Qinghua Xu and Qichun Zhang",

year = "2020",

month = apr,

doi = "10.1002/ajoc.202000101",

language = "English",

volume = "9",

pages = "579--583",

journal = "Asian Journal of Organic Chemistry",

issn = "2193-5807",

publisher = "John Wiley \& Sons",

number = "4",

}

TY - JOUR

T1 - Two-Photon Absorption of Butterfly-Shaped Carbonyl-Bridged Twistarene

AU - Wu, Xianglong

AU - Chen, Zhihui

AU - Chen, Wangqiao

AU - Yu, Fei

AU - Zhou, Guofu

AU - Xu, Qinghua

AU - Zhang, Qichun

PY - 2020/4

Y1 - 2020/4

N2 - The single crystals of a butterfly-shaped carbonyl-bridged twistarene 3 were obtained by slow diffusion of methanol into its chloroform solution. The single-crystal structure analysis indicated that 3 crystallized in a triclinic space group (P-1). The two-photon absorption (TPA) and nonlinear optical properties of single crystal of 3 were investigated in the range of 400 nm ∼650 nm. This is the first example of the TPA study based on single crystals made from the carbonyl-bridged twistarene. The corresponding TPA cross-section was found to be 3.69 GM at 800 nm.

AB - The single crystals of a butterfly-shaped carbonyl-bridged twistarene 3 were obtained by slow diffusion of methanol into its chloroform solution. The single-crystal structure analysis indicated that 3 crystallized in a triclinic space group (P-1). The two-photon absorption (TPA) and nonlinear optical properties of single crystal of 3 were investigated in the range of 400 nm ∼650 nm. This is the first example of the TPA study based on single crystals made from the carbonyl-bridged twistarene. The corresponding TPA cross-section was found to be 3.69 GM at 800 nm.

KW - Computational chemistry

KW - Crystal structure

KW - Fluorescence spectroscopy

KW - Twistarene

KW - Two-photon absorption

KW - Computational chemistry

KW - Crystal structure

KW - Fluorescence spectroscopy

KW - Twistarene

KW - Two-photon absorption

KW - Computational chemistry

KW - Crystal structure

KW - Fluorescence spectroscopy

KW - Twistarene

KW - Two-photon absorption

UR - https://www.scopus.com/pages/publications/85081742823

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85081742823&origin=recordpage

U2 - 10.1002/ajoc.202000101

DO - 10.1002/ajoc.202000101

M3 - RGC 21 - Publication in refereed journal

SN - 2193-5807

VL - 9

SP - 579

EP - 583

JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

IS - 4

ER -

Two-Photon Absorption of Butterfly-Shaped Carbonyl-Bridged Twistarene

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Research Keywords

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