Two-Photon Absorption in Quadrupolar Bis(acceptor)-Terminated Chromophores with Electron-Rich Bis(heterocycle)vinylene Bridges

Shijun Zheng; Amalia Leclercq; Jie Fu; Luca Beverina; Lazaro A. Padilha; Egbert Zojer; Karin Schmidt; Stephen Barlow; Jingdong Luo; Sei-Hum Jiang; Alex K.-Y. Jen; Yuanping Yi; Zhigang Shuai; Eric W. Van Stryland; David J. Hagan; Jean-Luc Brédas; Seth R. Marder

doi:10.1021/cm061681l

Two-Photon Absorption in Quadrupolar Bis(acceptor)-Terminated Chromophores with Electron-Rich Bis(heterocycle)vinylene Bridges

Shijun Zheng
, Amalia Leclercq
, Jie Fu
, Luca Beverina
, Lazaro A. Padilha
, Egbert Zojer
, Karin Schmidt
, Stephen Barlow
, Jingdong Luo
, Sei-Hum Jiang
, Alex K.-Y. Jen
, Yuanping Yi
, Zhigang Shuai
, Eric W. Van Stryland
, David J. Hagan
, Jean-Luc Brédas
, Seth R. Marder^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

73 Citations (Scopus)

Abstract

Two-photon absorption spectra for a range of bis(acceptor)-substituted bis(dibutoxythienyl)ethene and bis(N-hexylpyrrolyl)ethene chromophores have been recorded using Z-scan and white-light-continuum pump-probe techniques. All the chromophores studied show strong near-infrared two-photon absorption with cross sections in the range of 2400-5900 GM (1 GM = 1 × 10^-50 cm⁴ s/photon) at photon wavelengths between 1.0 and 1.3 μm; cross sections as high as 10000 GM can be accessed close to the one-photon absorption edge. Quantum-chemical calculations reproduce the experimentally observed variations of the two-photon properties with the chemical structure.

Original language	English
Pages (from-to)	432-442
Journal	Chemistry of Materials
Volume	19
Issue number	3
Online published	13 Jan 2007
DOIs	https://doi.org/10.1021/cm061681l
Publication status	Published - 6 Feb 2007
Externally published	Yes

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Zheng, S., Leclercq, A., Fu, J., Beverina, L., Padilha, L. A., Zojer, E., Schmidt, K., Barlow, S., Luo, J., Jiang, S.-H., Jen, A. K.-Y., Yi, Y., Shuai, Z., Van Stryland, E. W., Hagan, D. J., Brédas, J.-L., & Marder, S. R. (2007). Two-Photon Absorption in Quadrupolar Bis(acceptor)-Terminated Chromophores with Electron-Rich Bis(heterocycle)vinylene Bridges. Chemistry of Materials, 19(3), 432-442. https://doi.org/10.1021/cm061681l

@article{800020258ddf4815a8b07d459b15e80b,

title = "Two-Photon Absorption in Quadrupolar Bis(acceptor)-Terminated Chromophores with Electron-Rich Bis(heterocycle)vinylene Bridges",

abstract = "Two-photon absorption spectra for a range of bis(acceptor)-substituted bis(dibutoxythienyl)ethene and bis(N-hexylpyrrolyl)ethene chromophores have been recorded using Z-scan and white-light-continuum pump-probe techniques. All the chromophores studied show strong near-infrared two-photon absorption with cross sections in the range of 2400-5900 GM (1 GM = 1 × 10-50 cm4 s/photon) at photon wavelengths between 1.0 and 1.3 μm; cross sections as high as 10000 GM can be accessed close to the one-photon absorption edge. Quantum-chemical calculations reproduce the experimentally observed variations of the two-photon properties with the chemical structure.",

author = "Shijun Zheng and Amalia Leclercq and Jie Fu and Luca Beverina and Padilha, \{Lazaro A.\} and Egbert Zojer and Karin Schmidt and Stephen Barlow and Jingdong Luo and Sei-Hum Jiang and Jen, \{Alex K.-Y.\} and Yuanping Yi and Zhigang Shuai and \{Van Stryland\}, \{Eric W.\} and Hagan, \{David J.\} and Jean-Luc Br{\'e}das and Marder, \{Seth R.\}",

year = "2007",

month = feb,

day = "6",

doi = "10.1021/cm061681l",

language = "English",

volume = "19",

pages = "432--442",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "3",

}

Zheng, S, Leclercq, A, Fu, J, Beverina, L, Padilha, LA, Zojer, E, Schmidt, K, Barlow, S, Luo, J, Jiang, S-H, Jen, AK-Y, Yi, Y, Shuai, Z, Van Stryland, EW, Hagan, DJ, Brédas, J-L & Marder, SR 2007, 'Two-Photon Absorption in Quadrupolar Bis(acceptor)-Terminated Chromophores with Electron-Rich Bis(heterocycle)vinylene Bridges', Chemistry of Materials, vol. 19, no. 3, pp. 432-442. https://doi.org/10.1021/cm061681l

TY - JOUR

T1 - Two-Photon Absorption in Quadrupolar Bis(acceptor)-Terminated Chromophores with Electron-Rich Bis(heterocycle)vinylene Bridges

AU - Zheng, Shijun

AU - Leclercq, Amalia

AU - Fu, Jie

AU - Beverina, Luca

AU - Padilha, Lazaro A.

AU - Zojer, Egbert

AU - Schmidt, Karin

AU - Barlow, Stephen

AU - Luo, Jingdong

AU - Jiang, Sei-Hum

AU - Jen, Alex K.-Y.

AU - Yi, Yuanping

AU - Shuai, Zhigang

AU - Van Stryland, Eric W.

AU - Hagan, David J.

AU - Brédas, Jean-Luc

AU - Marder, Seth R.

PY - 2007/2/6

Y1 - 2007/2/6

N2 - Two-photon absorption spectra for a range of bis(acceptor)-substituted bis(dibutoxythienyl)ethene and bis(N-hexylpyrrolyl)ethene chromophores have been recorded using Z-scan and white-light-continuum pump-probe techniques. All the chromophores studied show strong near-infrared two-photon absorption with cross sections in the range of 2400-5900 GM (1 GM = 1 × 10-50 cm4 s/photon) at photon wavelengths between 1.0 and 1.3 μm; cross sections as high as 10000 GM can be accessed close to the one-photon absorption edge. Quantum-chemical calculations reproduce the experimentally observed variations of the two-photon properties with the chemical structure.

AB - Two-photon absorption spectra for a range of bis(acceptor)-substituted bis(dibutoxythienyl)ethene and bis(N-hexylpyrrolyl)ethene chromophores have been recorded using Z-scan and white-light-continuum pump-probe techniques. All the chromophores studied show strong near-infrared two-photon absorption with cross sections in the range of 2400-5900 GM (1 GM = 1 × 10-50 cm4 s/photon) at photon wavelengths between 1.0 and 1.3 μm; cross sections as high as 10000 GM can be accessed close to the one-photon absorption edge. Quantum-chemical calculations reproduce the experimentally observed variations of the two-photon properties with the chemical structure.

UR - https://www.scopus.com/pages/publications/33847217301

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-33847217301&origin=recordpage

U2 - 10.1021/cm061681l

DO - 10.1021/cm061681l

M3 - RGC 21 - Publication in refereed journal

SN - 0897-4756

VL - 19

SP - 432

EP - 442

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 3

ER -

Two-Photon Absorption in Quadrupolar Bis(acceptor)-Terminated Chromophores with Electron-Rich Bis(heterocycle)vinylene Bridges

Abstract

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