Two isomeric zeolite-like metal-organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

Shuang Peng; Yan-Jie Qi; Xin-Hao Li; Cai Sun; Ling-Yun Li; Xin-Xiong Li; Shou-Tian Zheng; Qichun Zhang

doi:10.1039/d1ce00464f

Two isomeric zeolite-like metal-organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

Shuang Peng
, Yan-Jie Qi
, Xin-Hao Li
, Cai Sun
, Ling-Yun Li
, Xin-Xiong Li^*
, Shou-Tian Zheng
, Qichun Zhang^*

^*Corresponding author for this work

Centre of Super-Diamond and Advanced Films

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

9 Citations (Scopus)

Abstract

Two isomeric zeolite-like metal-organic frameworks with the formula of [(CH₃)₂NH₂][Cd(TPO)]⋅xsolvent were successfully prepared and characterized. Both frameworks are constructed from tetrahedral TPO^3- nodes and tetrahedrally connected Cd²⁺ nodes, representing rare examples of zeolite-like MOFs with an isomeric characteristic. Moreover, one of the frameworks shows mechanically responsive luminescence emission after the crystals are ground for different times. Additionally, it has permanent porosity, and can selectively adsorb CO₂ over N₂.

Original language	English
Pages (from-to)	5753-5757
Number of pages	5
Journal	CrystEngComm
Volume	23
Issue number	34
Online published	13 May 2021
DOIs	https://doi.org/10.1039/d1ce00464f
Publication status	Published - 14 Sept 2021

Research Keywords

COORDINATION
DESIGN
DIVERSITY
STABILITY
COCRYSTAL
TOPOLOGY
SORPTION
SOLVENT
OXIDE
SHAPE

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abstract = "Two isomeric zeolite-like metal-organic frameworks with the formula of [(CH3)2NH2][Cd(TPO)]⋅xsolvent were successfully prepared and characterized. Both frameworks are constructed from tetrahedral TPO3- nodes and tetrahedrally connected Cd2+ nodes, representing rare examples of zeolite-like MOFs with an isomeric characteristic. Moreover, one of the frameworks shows mechanically responsive luminescence emission after the crystals are ground for different times. Additionally, it has permanent porosity, and can selectively adsorb CO2 over N2.",

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author = "Shuang Peng and Yan-Jie Qi and Xin-Hao Li and Cai Sun and Ling-Yun Li and Xin-Xiong Li and Shou-Tian Zheng and Qichun Zhang",

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AU - Peng, Shuang

AU - Qi, Yan-Jie

AU - Li, Xin-Hao

AU - Sun, Cai

AU - Li, Ling-Yun

AU - Li, Xin-Xiong

AU - Zheng, Shou-Tian

AU - Zhang, Qichun

PY - 2021/9/14

Y1 - 2021/9/14

N2 - Two isomeric zeolite-like metal-organic frameworks with the formula of [(CH3)2NH2][Cd(TPO)]⋅xsolvent were successfully prepared and characterized. Both frameworks are constructed from tetrahedral TPO3- nodes and tetrahedrally connected Cd2+ nodes, representing rare examples of zeolite-like MOFs with an isomeric characteristic. Moreover, one of the frameworks shows mechanically responsive luminescence emission after the crystals are ground for different times. Additionally, it has permanent porosity, and can selectively adsorb CO2 over N2.

AB - Two isomeric zeolite-like metal-organic frameworks with the formula of [(CH3)2NH2][Cd(TPO)]⋅xsolvent were successfully prepared and characterized. Both frameworks are constructed from tetrahedral TPO3- nodes and tetrahedrally connected Cd2+ nodes, representing rare examples of zeolite-like MOFs with an isomeric characteristic. Moreover, one of the frameworks shows mechanically responsive luminescence emission after the crystals are ground for different times. Additionally, it has permanent porosity, and can selectively adsorb CO2 over N2.

KW - COORDINATION

KW - DESIGN

KW - DIVERSITY

KW - STABILITY

KW - COCRYSTAL

KW - TOPOLOGY

KW - SORPTION

KW - SOLVENT

KW - OXIDE

KW - SHAPE

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U2 - 10.1039/d1ce00464f

DO - 10.1039/d1ce00464f

M3 - RGC 21 - Publication in refereed journal

SN - 1466-8033

VL - 23

SP - 5753

EP - 5757

JO - CrystEngComm

JF - CrystEngComm

IS - 34

ER -

Two isomeric zeolite-like metal-organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

Abstract

Research Keywords

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