Abstract
The electronic configuration is crucial in governing the binding strength of intermediates with catalysts, yet it is still challenging to control the catalysts’ surface electronic spin state. Here, it is demonstrated that through surface metal–organic framework transformation followed by acid etching, the electronic spin state of surface Co<sup>3+</sup> ions on spinel Co<sub>3</sub>O<sub>4</sub> can be transformed from t<sub>2g</sub> 6 to the high electronic spin state of t<sub>2g</sub><sup>4</sup>e<sub>g</sub> 2 by expanding the surface lattice constant, which significantly enhances the overlap of the e<sub>g</sub> orbital of cobalt with the oxygen adsorbates, and greatly improves the intermediates adsorption and thus the oxygen evolution reaction activity. The high electronic spin rich Co<sub>3</sub>O<sub>4</sub> electrode exhibits an anodic current density of 10 mA cm<sup>−2</sup> at an overpotential of 280 mV. The finding offers a rational design strategy to manipulate the electronic spin state of catalyst and the hybridization of molecular orbitals in water electrolysis. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Original language | English |
|---|---|
| Article number | 1800001 |
| Journal | Small Methods |
| Volume | 2 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 11 May 2018 |
| Externally published | Yes |
Bibliographical note
Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].Research Keywords
- adsorption
- oxygen Evolution
- spin State
- spinel
- strain