Transition metal catalysis in fluorous media : Practical application of a new immobilization principle to rhodium-catalyzed hydroboration
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 1610-1612 |
| Journal / Publication | Angewandte Chemie - International Edition in English |
| Volume | 36 |
| Issue number | 15 |
| Publication status | Published - 1997 |
| Externally published | Yes |
Link(s)
Abstract
The 'Teflon greaseball' [RhCl{P[CH2CH2(CF2)5CF3]3}3] (1) is highly soluble in CF3C6F11 and catalyzes a variety of organic transformations. The products can be extracted with organic solvents, and the solution of 1 reused. This environmentally friendly protocol is showcased for hydroboration, in which the customary oxidative workup destroys the metal catalyst. Catalyst loadings of only 0.01-0.25 mol% are effective under mild conditions (25-40 °C, 1-40 h) and give turnover numbers as high as 8500.
Research Area(s)
- Fluorocarbons, Hydroborations, Immobilization, Rhodium, Two-phase catalysis
Citation Format(s)
Transition metal catalysis in fluorous media : Practical application of a new immobilization principle to rhodium-catalyzed hydroboration. / Juliette, J. J J; Horvath, I. T.; Gladysz, J. A.
In: Angewandte Chemie - International Edition in English, Vol. 36, No. 15, 1997, p. 1610-1612.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
