Thermal degradation study of interpenetrating polymer network based on modified bismaleimide resin and cyanate ester

Jing Fan; Xiao Hu; Chee Yoon Yue

doi:10.1002/pi.962

Thermal degradation study of interpenetrating polymer network based on modified bismaleimide resin and cyanate ester

Jing Fan
, Xiao Hu
, Chee Yoon Yue

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

62 Citations (Scopus)

Abstract

Interpenetrating polymer networks (IPNs) based on different ratios of a modified bismaleimide resin (BMI/DBA) and cyanate ester (b10) have been synthesized via prepolymerization followed by thermal curing. A systematic thermal degradation study of these new BMI/DBA-CE IPN resin systems was conducted by thermogravimetric analysis at different heating rates both in N₂ (thermal stability) and in air (thermal-oxidative stability). The cured BMI/DBA-CE IPN resin systems show excellent thermal stability, which could be demonstrated by 5% weight loss temperature (T_5%) ranging between 409 and 423 °C, maximum decomposition rate temperature (T_max) ranging between 423 and 451 °C, and the char yields at 800 °C ranging from 37% to 41% in nitrogen at a heating rate of 10°C min^-1. The apparent activation energy associated with the main degradation stage of the cured BMI/DBA-CE IPN resin systems was determined using the Kissinger method. The obtained results provide useful information in drawing correlation between thermal properties and structure. © 2003 Society of Chemical Industry.

Original language	English
Pages (from-to)	15-22
Journal	Polymer International
Volume	52
Issue number	1
DOIs	https://doi.org/10.1002/pi.962
Publication status	Published - Jan 2003
Externally published	Yes

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Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Research Keywords

Bismaleimide
Cyanate ester
Interpenetrating polymer network
Thermal degradation and activation energy

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title = "Thermal degradation study of interpenetrating polymer network based on modified bismaleimide resin and cyanate ester",

abstract = "Interpenetrating polymer networks (IPNs) based on different ratios of a modified bismaleimide resin (BMI/DBA) and cyanate ester (b10) have been synthesized via prepolymerization followed by thermal curing. A systematic thermal degradation study of these new BMI/DBA-CE IPN resin systems was conducted by thermogravimetric analysis at different heating rates both in N2 (thermal stability) and in air (thermal-oxidative stability). The cured BMI/DBA-CE IPN resin systems show excellent thermal stability, which could be demonstrated by 5\% weight loss temperature (T5\%) ranging between 409 and 423 °C, maximum decomposition rate temperature (Tmax) ranging between 423 and 451 °C, and the char yields at 800 °C ranging from 37\% to 41\% in nitrogen at a heating rate of 10°C min-1. The apparent activation energy associated with the main degradation stage of the cured BMI/DBA-CE IPN resin systems was determined using the Kissinger method. The obtained results provide useful information in drawing correlation between thermal properties and structure. {\textcopyright} 2003 Society of Chemical Industry.",

keywords = "Bismaleimide, Cyanate ester, Interpenetrating polymer network, Thermal degradation and activation energy",

author = "Jing Fan and Xiao Hu and Yue, \{Chee Yoon\}",

note = "Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected]. ",

year = "2003",

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journal = "Polymer International",

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T1 - Thermal degradation study of interpenetrating polymer network based on modified bismaleimide resin and cyanate ester

AU - Fan, Jing

AU - Hu, Xiao

AU - Yue, Chee Yoon

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 2003/1

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N2 - Interpenetrating polymer networks (IPNs) based on different ratios of a modified bismaleimide resin (BMI/DBA) and cyanate ester (b10) have been synthesized via prepolymerization followed by thermal curing. A systematic thermal degradation study of these new BMI/DBA-CE IPN resin systems was conducted by thermogravimetric analysis at different heating rates both in N2 (thermal stability) and in air (thermal-oxidative stability). The cured BMI/DBA-CE IPN resin systems show excellent thermal stability, which could be demonstrated by 5% weight loss temperature (T5%) ranging between 409 and 423 °C, maximum decomposition rate temperature (Tmax) ranging between 423 and 451 °C, and the char yields at 800 °C ranging from 37% to 41% in nitrogen at a heating rate of 10°C min-1. The apparent activation energy associated with the main degradation stage of the cured BMI/DBA-CE IPN resin systems was determined using the Kissinger method. The obtained results provide useful information in drawing correlation between thermal properties and structure. © 2003 Society of Chemical Industry.

AB - Interpenetrating polymer networks (IPNs) based on different ratios of a modified bismaleimide resin (BMI/DBA) and cyanate ester (b10) have been synthesized via prepolymerization followed by thermal curing. A systematic thermal degradation study of these new BMI/DBA-CE IPN resin systems was conducted by thermogravimetric analysis at different heating rates both in N2 (thermal stability) and in air (thermal-oxidative stability). The cured BMI/DBA-CE IPN resin systems show excellent thermal stability, which could be demonstrated by 5% weight loss temperature (T5%) ranging between 409 and 423 °C, maximum decomposition rate temperature (Tmax) ranging between 423 and 451 °C, and the char yields at 800 °C ranging from 37% to 41% in nitrogen at a heating rate of 10°C min-1. The apparent activation energy associated with the main degradation stage of the cured BMI/DBA-CE IPN resin systems was determined using the Kissinger method. The obtained results provide useful information in drawing correlation between thermal properties and structure. © 2003 Society of Chemical Industry.

KW - Bismaleimide

KW - Cyanate ester

KW - Interpenetrating polymer network

KW - Thermal degradation and activation energy

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U2 - 10.1002/pi.962

DO - 10.1002/pi.962

M3 - RGC 21 - Publication in refereed journal

SN - 0959-8103

VL - 52

SP - 15

EP - 22

JO - Polymer International

JF - Polymer International

IS - 1

ER -

Thermal degradation study of interpenetrating polymer network based on modified bismaleimide resin and cyanate ester

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