Theory-guided enhancement of poling efficiency of organic electro-optic materials

Stephanie J. Benight; Lewis E. Johnson; Daniel B. Knorr; Denise H. Bale; Ilya Kosilkin; Benjamin C. Olbricht; Philip A. Sullivan; Philip J. Reid; Bruce H. Robinson; Rene M. Overney; Alex K.-Y. Jen; William H. Steier; Seong-Ku Kim; Harold Fetterman; Dennis W. Prather; Larry R. Dalton

doi:10.1117/12.862059

Theory-guided enhancement of poling efficiency of organic electro-optic materials

Stephanie J. Benight
, Lewis E. Johnson
, Daniel B. Knorr
, Denise H. Bale
, Ilya Kosilkin
, Benjamin C. Olbricht
, Philip A. Sullivan
, Philip J. Reid
, Bruce H. Robinson
, Rene M. Overney
, Alex K.-Y. Jen
, William H. Steier
, Seong-Ku Kim
, Harold Fetterman
, Dennis W. Prather
, Larry R. Dalton

Research output: Chapters, Conference Papers, Creative and Literary Works › RGC 32 - Refereed conference paper (with host publication) › peer-review

5 Citations (Scopus)

Abstract

Theoretical calculations have demonstrated that the ratio of second and third degree order parameters can define lattice dimensionality and furthermore, that an increased ratio of second to third degree order parameters represents reduced lattice dimensionality. As a result, the third degree order parameter (i.e. acentric order parameter) is increased, causing an increase in electro-optic activity with reduced lattice dimensionality. Experimentally, specific spatially-anisotropic interactions associated with coumarin moieties and Frechet-type (arene/perfluoroarene) dendrons have been incorporated into chromophore systems and have been shown to lead to lattices of reduced dimensionality, resulting in increased values of the acentric order parameter and therefore, electro-optic activity. Reductions in lattice dimensionality can also arise from guest chromophore-host chromophore interactions in binary chromophore organic glasses and from laserinduced ordering of host lattice chromophores observed in the laser-assisted electric field poling of azo-dye-containing host lattices. These interactions in various chromophore systems including investigation of EO and order properties are discussed. © 2010 SPIE.

Original language	English
Title of host publication	Linear and Nonlinear Optics of Organic Materials X
Editors	Manfred Eich, Jean-Michel Nunz, Rachel Jakubiak, Theodore G. Goodson III
Publisher	SPIE
ISBN (Print)	9780819482709
DOIs	https://doi.org/10.1117/12.862059
Publication status	Published - 18 Aug 2010
Externally published	Yes
Event	SPIE Optics + Photonics 2010 - San Diego Convention Center, San Diego, CA, United States Duration: 1 Aug 2010 → 5 Aug 2010 https://spie.org/Documents/ConferencesExhibitions/OP10-Final-lr.pdf https://www.grss-ieee.org/events/photonic-devices-applications-2010-part-of-spie-optics-photonics/ https://www.internano.org/node/301

Publication series

Name	Proceedings of SPIE
Volume	7774
ISSN (Print)	0277-786X

Conference

Conference	SPIE Optics + Photonics 2010
Place	United States
City	San Diego, CA
Period	1/08/10 → 5/08/10
Internet address	https://spie.org/Documents/ConferencesExhibitions/OP10-Final-lr.pdf https://www.grss-ieee.org/events/photonic-devices-applications-2010-part-of-spie-optics-photonics/ https://www.internano.org/node/301

Research Keywords

Dielectric permittivity
Electric field poling
Electro-optic chromophores
Lattice dimensionality
Molecular first hyperpolarizability
Monte Carlo methods
Order parameters
Spatially-anisotropic intermolecular electrostatic interactions

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Benight, S. J., Johnson, L. E., Knorr, D. B., Bale, D. H., Kosilkin, I., Olbricht, B. C., Sullivan, P. A., Reid, P. J., Robinson, B. H., Overney, R. M., Jen, A. K.-Y., Steier, W. H., Kim, S.-K., Fetterman, H., Prather, D. W., & Dalton, L. R. (2010). Theory-guided enhancement of poling efficiency of organic electro-optic materials. In M. Eich, J.-M. Nunz, R. Jakubiak, & T. G. Goodson III (Eds.), Linear and Nonlinear Optics of Organic Materials X Article 77740F (Proceedings of SPIE; Vol. 7774). SPIE. https://doi.org/10.1117/12.862059

@inproceedings{3722781020bf4df4bce405156e388b89,

title = "Theory-guided enhancement of poling efficiency of organic electro-optic materials",

abstract = "Theoretical calculations have demonstrated that the ratio of second and third degree order parameters can define lattice dimensionality and furthermore, that an increased ratio of second to third degree order parameters represents reduced lattice dimensionality. As a result, the third degree order parameter (i.e. acentric order parameter) is increased, causing an increase in electro-optic activity with reduced lattice dimensionality. Experimentally, specific spatially-anisotropic interactions associated with coumarin moieties and Frechet-type (arene/perfluoroarene) dendrons have been incorporated into chromophore systems and have been shown to lead to lattices of reduced dimensionality, resulting in increased values of the acentric order parameter and therefore, electro-optic activity. Reductions in lattice dimensionality can also arise from guest chromophore-host chromophore interactions in binary chromophore organic glasses and from laserinduced ordering of host lattice chromophores observed in the laser-assisted electric field poling of azo-dye-containing host lattices. These interactions in various chromophore systems including investigation of EO and order properties are discussed. {\textcopyright} 2010 SPIE.",

keywords = "Dielectric permittivity, Electric field poling, Electro-optic chromophores, Lattice dimensionality, Molecular first hyperpolarizability, Monte Carlo methods, Order parameters, Spatially-anisotropic intermolecular electrostatic interactions",

author = "Benight, \{Stephanie J.\} and Johnson, \{Lewis E.\} and Knorr, \{Daniel B.\} and Bale, \{Denise H.\} and Ilya Kosilkin and Olbricht, \{Benjamin C.\} and Sullivan, \{Philip A.\} and Reid, \{Philip J.\} and Robinson, \{Bruce H.\} and Overney, \{Rene M.\} and Jen, \{Alex K.-Y.\} and Steier, \{William H.\} and Seong-Ku Kim and Harold Fetterman and Prather, \{Dennis W.\} and Dalton, \{Larry R.\}",

year = "2010",

month = aug,

day = "18",

doi = "10.1117/12.862059",

language = "English",

isbn = "9780819482709",

series = "Proceedings of SPIE",

publisher = "SPIE",

editor = "Manfred Eich and Jean-Michel Nunz and Rachel Jakubiak and \{Goodson III\}, \{Theodore G.\}",

booktitle = "Linear and Nonlinear Optics of Organic Materials X",

address = "United States",

note = "SPIE Optics + Photonics 2010 ; Conference date: 01-08-2010 Through 05-08-2010",

url = "https://spie.org/Documents/ConferencesExhibitions/OP10-Final-lr.pdf, https://www.grss-ieee.org/events/photonic-devices-applications-2010-part-of-spie-optics-photonics/, https://www.internano.org/node/301",

}

Benight, SJ, Johnson, LE, Knorr, DB, Bale, DH, Kosilkin, I, Olbricht, BC, Sullivan, PA, Reid, PJ, Robinson, BH, Overney, RM, Jen, AK-Y, Steier, WH, Kim, S-K, Fetterman, H, Prather, DW & Dalton, LR 2010, Theory-guided enhancement of poling efficiency of organic electro-optic materials. in M Eich, J-M Nunz, R Jakubiak & TG Goodson III (eds), Linear and Nonlinear Optics of Organic Materials X., 77740F, Proceedings of SPIE, vol. 7774, SPIE, SPIE Optics + Photonics 2010, San Diego, CA, United States, 1/08/10. https://doi.org/10.1117/12.862059

Theory-guided enhancement of poling efficiency of organic electro-optic materials. / Benight, Stephanie J.; Johnson, Lewis E.; Knorr, Daniel B. et al.
Linear and Nonlinear Optics of Organic Materials X. ed. / Manfred Eich; Jean-Michel Nunz; Rachel Jakubiak; Theodore G. Goodson III. SPIE, 2010. 77740F (Proceedings of SPIE; Vol. 7774).

Research output: Chapters, Conference Papers, Creative and Literary Works › RGC 32 - Refereed conference paper (with host publication) › peer-review

TY - GEN

T1 - Theory-guided enhancement of poling efficiency of organic electro-optic materials

AU - Benight, Stephanie J.

AU - Johnson, Lewis E.

AU - Knorr, Daniel B.

AU - Bale, Denise H.

AU - Kosilkin, Ilya

AU - Olbricht, Benjamin C.

AU - Sullivan, Philip A.

AU - Reid, Philip J.

AU - Robinson, Bruce H.

AU - Overney, Rene M.

AU - Jen, Alex K.-Y.

AU - Steier, William H.

AU - Kim, Seong-Ku

AU - Fetterman, Harold

AU - Prather, Dennis W.

AU - Dalton, Larry R.

PY - 2010/8/18

Y1 - 2010/8/18

N2 - Theoretical calculations have demonstrated that the ratio of second and third degree order parameters can define lattice dimensionality and furthermore, that an increased ratio of second to third degree order parameters represents reduced lattice dimensionality. As a result, the third degree order parameter (i.e. acentric order parameter) is increased, causing an increase in electro-optic activity with reduced lattice dimensionality. Experimentally, specific spatially-anisotropic interactions associated with coumarin moieties and Frechet-type (arene/perfluoroarene) dendrons have been incorporated into chromophore systems and have been shown to lead to lattices of reduced dimensionality, resulting in increased values of the acentric order parameter and therefore, electro-optic activity. Reductions in lattice dimensionality can also arise from guest chromophore-host chromophore interactions in binary chromophore organic glasses and from laserinduced ordering of host lattice chromophores observed in the laser-assisted electric field poling of azo-dye-containing host lattices. These interactions in various chromophore systems including investigation of EO and order properties are discussed. © 2010 SPIE.

AB - Theoretical calculations have demonstrated that the ratio of second and third degree order parameters can define lattice dimensionality and furthermore, that an increased ratio of second to third degree order parameters represents reduced lattice dimensionality. As a result, the third degree order parameter (i.e. acentric order parameter) is increased, causing an increase in electro-optic activity with reduced lattice dimensionality. Experimentally, specific spatially-anisotropic interactions associated with coumarin moieties and Frechet-type (arene/perfluoroarene) dendrons have been incorporated into chromophore systems and have been shown to lead to lattices of reduced dimensionality, resulting in increased values of the acentric order parameter and therefore, electro-optic activity. Reductions in lattice dimensionality can also arise from guest chromophore-host chromophore interactions in binary chromophore organic glasses and from laserinduced ordering of host lattice chromophores observed in the laser-assisted electric field poling of azo-dye-containing host lattices. These interactions in various chromophore systems including investigation of EO and order properties are discussed. © 2010 SPIE.

KW - Dielectric permittivity

KW - Electric field poling

KW - Electro-optic chromophores

KW - Lattice dimensionality

KW - Molecular first hyperpolarizability

KW - Monte Carlo methods

KW - Order parameters

KW - Spatially-anisotropic intermolecular electrostatic interactions

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DO - 10.1117/12.862059

M3 - RGC 32 - Refereed conference paper (with host publication)

SN - 9780819482709

T3 - Proceedings of SPIE

BT - Linear and Nonlinear Optics of Organic Materials X

A2 - Eich, Manfred

A2 - Nunz, Jean-Michel

A2 - Jakubiak, Rachel

A2 - Goodson III, Theodore G.

PB - SPIE

T2 - SPIE Optics + Photonics 2010

Y2 - 1 August 2010 through 5 August 2010

ER -

Theory-guided enhancement of poling efficiency of organic electro-optic materials

Abstract

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