The solubility of HCl in stratospheric aqueous aerosols and the depletion of ozone

K. S. Carslaw; P. Brimblecombe; S. L. Clegg; J. S A Green

doi:10.1016/0021-8502(92)90559-E

The solubility of HCl in stratospheric aqueous aerosols and the depletion of ozone

K. S. Carslaw
, P. Brimblecombe
, S. L. Clegg
, J. S A Green

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

1 Citation (Scopus)

Abstract

The solubility of HCl in aqueous sulphuric acid has been calculated using a Pitzer multicomponent thermodynamic model to 190K. The results suggest that at low temperatures the HCl content of the background stratospheric aerosol may be as high as 4 molal, greater than had been previously thought. This implies that aqueous stratospheric aerosols may be a site for the production of reactive chlorine during the polar winter. © 1992.

Original language	English
Pages (from-to)	909-912
Journal	Journal of Aerosol Science
Volume	23
Issue number	SUPPL. 1
DOIs	https://doi.org/10.1016/0021-8502(92)90559-E
Publication status	Published - 1992
Externally published	Yes

Research Keywords

atmospheric aerosols
Atmospheric chemistry
Henry's Law
solubility

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10.1016/0021-8502(92)90559-E

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title = "The solubility of HCl in stratospheric aqueous aerosols and the depletion of ozone",

abstract = "The solubility of HCl in aqueous sulphuric acid has been calculated using a Pitzer multicomponent thermodynamic model to 190K. The results suggest that at low temperatures the HCl content of the background stratospheric aerosol may be as high as 4 molal, greater than had been previously thought. This implies that aqueous stratospheric aerosols may be a site for the production of reactive chlorine during the polar winter. {\textcopyright} 1992.",

keywords = "atmospheric aerosols, Atmospheric chemistry, Henry's Law, solubility",

author = "Carslaw, \{K. S.\} and P. Brimblecombe and Clegg, \{S. L.\} and Green, \{J. S A\}",

year = "1992",

doi = "10.1016/0021-8502(92)90559-E",

language = "English",

volume = "23",

pages = "909--912",

journal = "Journal of Aerosol Science",

issn = "0021-8502",

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TY - JOUR

T1 - The solubility of HCl in stratospheric aqueous aerosols and the depletion of ozone

AU - Carslaw, K. S.

AU - Brimblecombe, P.

AU - Clegg, S. L.

AU - Green, J. S A

PY - 1992

Y1 - 1992

N2 - The solubility of HCl in aqueous sulphuric acid has been calculated using a Pitzer multicomponent thermodynamic model to 190K. The results suggest that at low temperatures the HCl content of the background stratospheric aerosol may be as high as 4 molal, greater than had been previously thought. This implies that aqueous stratospheric aerosols may be a site for the production of reactive chlorine during the polar winter. © 1992.

AB - The solubility of HCl in aqueous sulphuric acid has been calculated using a Pitzer multicomponent thermodynamic model to 190K. The results suggest that at low temperatures the HCl content of the background stratospheric aerosol may be as high as 4 molal, greater than had been previously thought. This implies that aqueous stratospheric aerosols may be a site for the production of reactive chlorine during the polar winter. © 1992.

KW - atmospheric aerosols

KW - Atmospheric chemistry

KW - Henry's Law

KW - solubility

UR - https://www.scopus.com/pages/publications/0026993222

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0026993222&origin=recordpage

U2 - 10.1016/0021-8502(92)90559-E

DO - 10.1016/0021-8502(92)90559-E

M3 - RGC 21 - Publication in refereed journal

SN - 0021-8502

VL - 23

SP - 909

EP - 912

JO - Journal of Aerosol Science

JF - Journal of Aerosol Science

IS - SUPPL. 1

ER -

The solubility of HCl in stratospheric aqueous aerosols and the depletion of ozone

Abstract

Research Keywords

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