The site selectivity of hydridge ligand in tungsten-triosmium clusters : the crystal structure and the solution dynamics of (C5Me5)WOs3(CO)12H
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 197-203 |
| Journal / Publication | Journal of Organometallic Chemistry |
| Volume | 371 |
| Issue number | 2 |
| Publication status | Published - 25 Jul 1989 |
| Externally published | Yes |
Link(s)
Abstract
The solid-state structure of a tetranuclear mixed-metal cluster (C5Me5)WOs3-(CO)12H (2b) which has hydride ligant bridging across a W-Os bond is presented. In solution, the isomer adopting the solid-state structure is in equilibrium with a second isomer (2a) in which the hydride is associated with an Os-Os edge. Complex 2 crystallizes in the orthorhombic space group Pna21 with a 21.598(6), b 8.973(4), c 14.121(4) Å, Z = 4; 2260 observed reflections with I > 3σ (I) were used in the refinement. The R values converged to RF = 0.023, Rw = 0.018 and GOF = 1.500.
Citation Format(s)
The site selectivity of hydridge ligand in tungsten-triosmium clusters : the crystal structure and the solution dynamics of (C5Me5)WOs3(CO)12H. / Peng, Shie-Ming; Lee, Gene-Hsiang; Chi, Yun et al.
In: Journal of Organometallic Chemistry, Vol. 371, No. 2, 25.07.1989, p. 197-203.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
