The role of calcium aluminate cement in developing an efficient ultra-high performance concrete resistant to explosive spalling under high temperatures

Conventional ordinary Portland cement (OPC)-based UHPC is vulnerable to explosive spalling under high temperatures. This study aims to classify the role of calcium aluminate cement (CAC) as the substitution for OPC in UHPC under high temperatures and finally develop an efficient UHPC without explosive spalling. It was found that CAC-based UHPC (UHPC-CAC) and OPC-based UHPC (UHPC-OPC) reached their peak strength both at 250 °C, but the peak strength (153.8 MPa) of UHPC-CAC was higher than that (137.5 MPa) of UHPC-OPC. Explosive spalling was found in UHPC-OPC after reaching 500 °C, while no spalling was observed in UHPC-CAC even at 1000 °C. The effectiveness of CAC in reducing the mechanical degradation and preventing the spalling of UHPC was attributed to three potential mechanisms: (1) CAC had less physically bound water to cause the vapor pressure in UHPC; (2) The main hydration product (i.e., calcium aluminosilicate hydrates) decomposed to a lesser extent, compared to the hydration product (i.e., calcium silicate hydrates) of OPC, as proved by X-ray diffraction (XRD) analysis, Thermogravimetric analysis (TGA), and Fourier-transform infrared (FTIR) analysis; (3) there exists pores coarsening in UHPC-CAC, as evidenced by micro-XCT, which could release the water pressure in UHPC and thus prevent the spalling at elevated temperatures. © 2023 Elsevier Ltd