The reactivity of acetylenes coordinated to cobalt. III. Reaction of the butene-2-olide-4 complexes, (C4O2R1)Co2(CO)7 with acetylenes; formation of new types of organic ligands

Gyula Váradi; István T. Horváth; Gyula Pályi; László Markó; Yurii L. Slovokhotov; Yurii T. Struchkov

doi:10.1016/S0022-328X(00)93470-3

The reactivity of acetylenes coordinated to cobalt. III. Reaction of the butene-2-olide-4 complexes, (C₄O₂R¹)Co₂(CO)₇ with acetylenes; formation of new types of organic ligands

Gyula Váradi
, István T. Horváth
, Gyula Pályi
, László Markó
, Yurii L. Slovokhotov
, Yurii T. Struchkov

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

11 Citations (Scopus)

Abstract

The "lactone" complexes, (C₄O₂R¹,R²)Co₂(CO)₇, [μ₂-carbonyl)[μ₂-spiro-(2,3-substituted-2-butene-4-olide-4-ylidene)] [bis(tricarbonyl-cobalt)(CoCo) derivatives, were found to react with acetylenes (R³C₂R⁴. This reaction yields the known acetylene complexes (R³C₂R⁴Co₂(CO)₆ and two isomeric compounds with the composition [(C₄O₂R¹,R²)(R³C₂R⁴)₂]Co₂(CO)₅. Spectroscopic arguments and X-ray structure determination show that both isomers contain σ, π-C₅ ligands bonded to both Co atoms. The structures of these isomerswere identified. © 1981.

Original language	English
Pages (from-to)	119-130
Journal	Journal of Organometallic Chemistry
Volume	206
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)93470-3
Publication status	Published - 17 Feb 1981
Externally published	Yes

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Váradi, G., Horváth, I. T., Pályi, G., Markó, L., Slovokhotov, Y. L., & Struchkov, Y. T. (1981). The reactivity of acetylenes coordinated to cobalt. III. Reaction of the butene-2-olide-4 complexes, (C₄O₂R¹)Co₂(CO)₇ with acetylenes; formation of new types of organic ligands. Journal of Organometallic Chemistry, 206(1), 119-130. https://doi.org/10.1016/S0022-328X(00)93470-3

@article{92e25b18f0674827812a1a372f2f1499,

title = "The reactivity of acetylenes coordinated to cobalt. III. Reaction of the butene-2-olide-4 complexes, (C4O2R1)Co2(CO)7 with acetylenes; formation of new types of organic ligands",

abstract = "The {"}lactone{"} complexes, (C4O2R1,R2)Co2(CO)7, [μ2-carbonyl)[μ2-spiro-(2,3-substituted-2-butene-4-olide-4-ylidene)] [bis(tricarbonyl-cobalt)(CoCo) derivatives, were found to react with acetylenes (R3C2R4. This reaction yields the known acetylene complexes (R3C2R4Co2(CO)6 and two isomeric compounds with the composition [(C4O2R1,R2)(R3C2R4)2]Co2(CO)5. Spectroscopic arguments and X-ray structure determination show that both isomers contain σ, π-C5 ligands bonded to both Co atoms. The structures of these isomerswere identified. {\textcopyright} 1981.",

author = "Gyula V{\'a}radi and Horv{\'a}th, \{Istv{\'a}n T.\} and Gyula P{\'a}lyi and L{\'a}szl{\'o} Mark{\'o} and Slovokhotov, \{Yurii L.\} and Struchkov, \{Yurii T.\}",

year = "1981",

month = feb,

day = "17",

doi = "10.1016/S0022-328X(00)93470-3",

language = "English",

volume = "206",

pages = "119--130",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1",

}

Váradi, G, Horváth, IT, Pályi, G, Markó, L, Slovokhotov, YL & Struchkov, YT 1981, 'The reactivity of acetylenes coordinated to cobalt. III. Reaction of the butene-2-olide-4 complexes, (C₄O₂R¹)Co₂(CO)₇ with acetylenes; formation of new types of organic ligands', Journal of Organometallic Chemistry, vol. 206, no. 1, pp. 119-130. https://doi.org/10.1016/S0022-328X(00)93470-3

The reactivity of acetylenes coordinated to cobalt. III. Reaction of the butene-2-olide-4 complexes, (C₄O₂R¹)Co₂(CO)₇ with acetylenes; formation of new types of organic ligands. / Váradi, Gyula; Horváth, István T.; Pályi, Gyula et al.
In: Journal of Organometallic Chemistry, Vol. 206, No. 1, 17.02.1981, p. 119-130.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - The reactivity of acetylenes coordinated to cobalt. III. Reaction of the butene-2-olide-4 complexes, (C4O2R1)Co2(CO)7 with acetylenes; formation of new types of organic ligands

AU - Váradi, Gyula

AU - Horváth, István T.

AU - Pályi, Gyula

AU - Markó, László

AU - Slovokhotov, Yurii L.

AU - Struchkov, Yurii T.

PY - 1981/2/17

Y1 - 1981/2/17

N2 - The "lactone" complexes, (C4O2R1,R2)Co2(CO)7, [μ2-carbonyl)[μ2-spiro-(2,3-substituted-2-butene-4-olide-4-ylidene)] [bis(tricarbonyl-cobalt)(CoCo) derivatives, were found to react with acetylenes (R3C2R4. This reaction yields the known acetylene complexes (R3C2R4Co2(CO)6 and two isomeric compounds with the composition [(C4O2R1,R2)(R3C2R4)2]Co2(CO)5. Spectroscopic arguments and X-ray structure determination show that both isomers contain σ, π-C5 ligands bonded to both Co atoms. The structures of these isomerswere identified. © 1981.

AB - The "lactone" complexes, (C4O2R1,R2)Co2(CO)7, [μ2-carbonyl)[μ2-spiro-(2,3-substituted-2-butene-4-olide-4-ylidene)] [bis(tricarbonyl-cobalt)(CoCo) derivatives, were found to react with acetylenes (R3C2R4. This reaction yields the known acetylene complexes (R3C2R4Co2(CO)6 and two isomeric compounds with the composition [(C4O2R1,R2)(R3C2R4)2]Co2(CO)5. Spectroscopic arguments and X-ray structure determination show that both isomers contain σ, π-C5 ligands bonded to both Co atoms. The structures of these isomerswere identified. © 1981.

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U2 - 10.1016/S0022-328X(00)93470-3

DO - 10.1016/S0022-328X(00)93470-3

M3 - RGC 21 - Publication in refereed journal

SN - 0022-328X

VL - 206

SP - 119

EP - 130

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -