The first series of chiral 2,2′ : 6′,2″-terpyridine tri-N-oxide ligands for Lewis base-catalyzed asymmetric allylation of aldehydes
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
---|---|
Pages (from-to) | 1967-1969 |
Journal / Publication | Organic and Biomolecular Chemistry |
Volume | 2 |
Issue number | 14 |
Publication status | Published - 21 Jul 2004 |
Link(s)
Abstract
The first series of chiral 2,2′:6′2″-terpyridine tri-N-oxide ligands have been developed; They were showed to be active Lewis base-catalysts for asymmetric allylation of aldehydes using allyltrichlorosilane with optimal results at 0°C for electron-deficient aromatic aldehydes (yields up to 97% and enantioselectivities up to 86% ee).
Citation Format(s)
The first series of chiral 2,2′: 6′,2″-terpyridine tri-N-oxide ligands for Lewis base-catalyzed asymmetric allylation of aldehydes. / Wong, Wing-Leung; Lee, Chi-Sing; Leung, Hon-Kit et al.
In: Organic and Biomolecular Chemistry, Vol. 2, No. 14, 21.07.2004, p. 1967-1969.
In: Organic and Biomolecular Chemistry, Vol. 2, No. 14, 21.07.2004, p. 1967-1969.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review