The effects of binding ligand variation on the nickel catalyzed externally initiated polymerization of 2-bromo-3-hexyl-5- iodothiophene

Natalia Doubina; Michelina Stoddard; Hugo A. Bronstein; Alex K.-Y. Jen; Christine K. Luscombe

doi:10.1002/macp.200900375

The effects of binding ligand variation on the nickel catalyzed externally initiated polymerization of 2-bromo-3-hexyl-5- iodothiophene

Natalia Doubina, Michelina Stoddard, Hugo A. Bronstein, Alex K.-Y. Jen, Christine K. Luscombe^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

46 Citations (Scopus)

Abstract

The effects of binding ligand variation on the externally initiated Ni catalyzed polymerization of P3HT were investigated using a novel methodology allowing facile screening of ligands. P3HT was synthesized with >80% initiator incorporation for both mono- and bidentate phosphine ligands. Variation of the initiating aryl group demonstrated vastly superior results for o-tolyl over p-tolyl substituents. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA Weinheim.

Original language	English
Pages (from-to)	1966-1972
Journal	Macromolecular Chemistry and Physics
Volume	210
Issue number	22
DOIs	https://doi.org/10.1002/macp.200900375
Publication status	Published - 24 Nov 2009
Externally published	Yes

Research Keywords

Catalysts
Chain
Growth
Polymerization
Polymerization (general)
Polythiophene
Semiconducting polymers

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10.1002/macp.200900375

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title = "The effects of binding ligand variation on the nickel catalyzed externally initiated polymerization of 2-bromo-3-hexyl-5- iodothiophene",

abstract = "The effects of binding ligand variation on the externally initiated Ni catalyzed polymerization of P3HT were investigated using a novel methodology allowing facile screening of ligands. P3HT was synthesized with >80% initiator incorporation for both mono- and bidentate phosphine ligands. Variation of the initiating aryl group demonstrated vastly superior results for o-tolyl over p-tolyl substituents. {\textcopyright} 2009 WILEY-VCH Verlag GmbH & Co. KGaA Weinheim.",

keywords = "Catalysts, Chain, Growth, Polymerization, Polymerization (general), Polythiophene, Semiconducting polymers",

author = "Natalia Doubina and Michelina Stoddard and Bronstein, {Hugo A.} and Jen, {Alex K.-Y.} and Luscombe, {Christine K.}",

year = "2009",

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day = "24",

doi = "10.1002/macp.200900375",

language = "English",

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journal = "Macromolecular Chemistry and Physics",

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}

The effects of binding ligand variation on the nickel catalyzed externally initiated polymerization of 2-bromo-3-hexyl-5- iodothiophene. / Doubina, Natalia; Stoddard, Michelina; Bronstein, Hugo A. et al.
In: Macromolecular Chemistry and Physics, Vol. 210, No. 22, 24.11.2009, p. 1966-1972.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - The effects of binding ligand variation on the nickel catalyzed externally initiated polymerization of 2-bromo-3-hexyl-5- iodothiophene

AU - Doubina, Natalia

AU - Stoddard, Michelina

AU - Bronstein, Hugo A.

AU - Jen, Alex K.-Y.

AU - Luscombe, Christine K.

PY - 2009/11/24

Y1 - 2009/11/24

N2 - The effects of binding ligand variation on the externally initiated Ni catalyzed polymerization of P3HT were investigated using a novel methodology allowing facile screening of ligands. P3HT was synthesized with >80% initiator incorporation for both mono- and bidentate phosphine ligands. Variation of the initiating aryl group demonstrated vastly superior results for o-tolyl over p-tolyl substituents. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA Weinheim.

AB - The effects of binding ligand variation on the externally initiated Ni catalyzed polymerization of P3HT were investigated using a novel methodology allowing facile screening of ligands. P3HT was synthesized with >80% initiator incorporation for both mono- and bidentate phosphine ligands. Variation of the initiating aryl group demonstrated vastly superior results for o-tolyl over p-tolyl substituents. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA Weinheim.

KW - Catalysts

KW - Chain

KW - Growth

KW - Polymerization

KW - Polymerization (general)

KW - Polythiophene

KW - Semiconducting polymers

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DO - 10.1002/macp.200900375

M3 - RGC 21 - Publication in refereed journal

SN - 1022-1352

VL - 210

SP - 1966

EP - 1972

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 22

ER -

The effects of binding ligand variation on the nickel catalyzed externally initiated polymerization of 2-bromo-3-hexyl-5- iodothiophene

Abstract

Research Keywords

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