The dissociation constant and henry's law constant of HCl in aqueous solution
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal
Author(s)
Detail(s)
Original language | English |
---|---|
Pages (from-to) | 2483-2485 |
Journal / Publication | Atmospheric Environment (1967) |
Volume | 20 |
Issue number | 12 |
Publication status | Published - 1986 |
Externally published | Yes |
Link(s)
Abstract
Descriptions of the solubility of HC1 in water involving Raoult's Law have been shown to be inappropriate. Henry's Law constants (KH) for reactions of the form: HX(g) = H(aq)
++X(aq)
- are recommended for strong acids on both theoretical and practical grounds. Solubilities of strong acids in electrolyte mixtures can be calculated using activity coefficient models and appropriate values of KH. A critical evaluation of experimental data yields KH equal to 2.04 × 106mol2kg-2atm-1 at 25°C for HCl. The solubility of weak acids, such as HF, is also discussed. © 1986.
Citation Format(s)
The dissociation constant and henry's law constant of HCl in aqueous solution. / Clegg, S. L.; Brimblecombe, P.
In: Atmospheric Environment (1967), Vol. 20, No. 12, 1986, p. 2483-2485.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal