The application of thiol-ene reaction on preparing UV curable bismaleimide-containing liquid formulations

Shiliang Fan; Freddy Y.C. Boey; Marc J.M. Abadie

doi:10.1016/j.eurpolymj.2008.04.024

The application of thiol-ene reaction on preparing UV curable bismaleimide-containing liquid formulations

Shiliang Fan, Freddy Y.C. Boey, Marc J.M. Abadie^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

20 Citations (Scopus)

Abstract

Thiol-ene reaction method was introduced to photopolymerize a new liquid formulation of commercial bismaleimide, as an alternative to traditional thermal cure method presently used for BMI in the industry. UV curing was shown to be an efficient method which promoted the reaction rate significantly and was able to achieve this at low temperatures (30-50 °C). The liquid formulation is stable and has low viscosity. The cure mechanism and cure kinetics were studied based on the data elucidated from the DPC and FTIR. The cured thin film can achieve very high thermal stability (∼400 °C) and BMI can retard the thermal degradation temperature and rate. Crown Copyright © 2008 Published by Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	2123-2129
Journal	European Polymer Journal
Volume	44
Issue number	7
Online published	22 Apr 2008
DOIs	https://doi.org/10.1016/j.eurpolymj.2008.04.024
Publication status	Published - Jul 2008
Externally published	Yes

Research Keywords

Bismaleimide
DPC
Formulation
Kinetics
Photopolymerization
Thiol-ene

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10.1016/j.eurpolymj.2008.04.024

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title = "The application of thiol-ene reaction on preparing UV curable bismaleimide-containing liquid formulations",

abstract = "Thiol-ene reaction method was introduced to photopolymerize a new liquid formulation of commercial bismaleimide, as an alternative to traditional thermal cure method presently used for BMI in the industry. UV curing was shown to be an efficient method which promoted the reaction rate significantly and was able to achieve this at low temperatures (30-50 °C). The liquid formulation is stable and has low viscosity. The cure mechanism and cure kinetics were studied based on the data elucidated from the DPC and FTIR. The cured thin film can achieve very high thermal stability (∼400 °C) and BMI can retard the thermal degradation temperature and rate. Crown Copyright {\textcopyright} 2008 Published by Elsevier Ltd. All rights reserved.",

keywords = "Bismaleimide, DPC, Formulation, Kinetics, Photopolymerization, Thiol-ene",

author = "Shiliang Fan and Boey, {Freddy Y.C.} and Abadie, {Marc J.M.}",

year = "2008",

month = jul,

doi = "10.1016/j.eurpolymj.2008.04.024",

language = "English",

volume = "44",

pages = "2123--2129",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Ltd.",

number = "7",

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TY - JOUR

T1 - The application of thiol-ene reaction on preparing UV curable bismaleimide-containing liquid formulations

AU - Fan, Shiliang

AU - Boey, Freddy Y.C.

AU - Abadie, Marc J.M.

PY - 2008/7

Y1 - 2008/7

N2 - Thiol-ene reaction method was introduced to photopolymerize a new liquid formulation of commercial bismaleimide, as an alternative to traditional thermal cure method presently used for BMI in the industry. UV curing was shown to be an efficient method which promoted the reaction rate significantly and was able to achieve this at low temperatures (30-50 °C). The liquid formulation is stable and has low viscosity. The cure mechanism and cure kinetics were studied based on the data elucidated from the DPC and FTIR. The cured thin film can achieve very high thermal stability (∼400 °C) and BMI can retard the thermal degradation temperature and rate. Crown Copyright © 2008 Published by Elsevier Ltd. All rights reserved.

AB - Thiol-ene reaction method was introduced to photopolymerize a new liquid formulation of commercial bismaleimide, as an alternative to traditional thermal cure method presently used for BMI in the industry. UV curing was shown to be an efficient method which promoted the reaction rate significantly and was able to achieve this at low temperatures (30-50 °C). The liquid formulation is stable and has low viscosity. The cure mechanism and cure kinetics were studied based on the data elucidated from the DPC and FTIR. The cured thin film can achieve very high thermal stability (∼400 °C) and BMI can retard the thermal degradation temperature and rate. Crown Copyright © 2008 Published by Elsevier Ltd. All rights reserved.

KW - Bismaleimide

KW - DPC

KW - Formulation

KW - Kinetics

KW - Photopolymerization

KW - Thiol-ene

UR - http://www.scopus.com/inward/record.url?scp=47249162807&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-47249162807&origin=recordpage

U2 - 10.1016/j.eurpolymj.2008.04.024

DO - 10.1016/j.eurpolymj.2008.04.024

M3 - RGC 21 - Publication in refereed journal

SN - 0014-3057

VL - 44

SP - 2123

EP - 2129

JO - European Polymer Journal

JF - European Polymer Journal

IS - 7

ER -

The application of thiol-ene reaction on preparing UV curable bismaleimide-containing liquid formulations

Abstract

Research Keywords

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