Temperature-responsive hydroxypropylcellulose based thermochromic material and its smart window application

Yong-Sheng Yang, Yang Zhou, Freddy Yin Chiang Boey*, Yi Long*

*Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

113 Citations (Scopus)

Abstract

Thermochromic materials are the most cost effective smart window materials and the organic hydrogel material has large solar modulating ability (ΔTsol) and the luminous transmittance (Tlum) compared with inorganic VO2 based materials. Here we report a green and new organic thermochromic material based on hydroxypropylcellulose. With increasing addition of NaCl from 0.5% (wt%) to 5% (wt%), the LCST (lower critical solution temperature) could reduce from 42 °C to 30 °C. The morphology change of freeze dried samples below and above LCST proves that the phase change of this hydroxypropylcellulose based hydrogel is due to the solubility change of the polymer in water. The fine-tuned recipe can give an outstanding solar modulating ability (ΔTsol) of 25.7% and high averaged Tlum of 67.4% with LCST of 38 °C. © The Royal Society of Chemistry 2016.
Original languageEnglish
Pages (from-to)61449-61453
JournalRSC Advances
Volume6
Issue number66
Online published22 Jun 2016
DOIs
Publication statusPublished - 2016
Externally publishedYes

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