Abstract
A series of luminescent coatings of Tb3+ functionalized coordination polymers (CPs) consolidated by different multi-carboxylic ligands [1,4-benzenedicarboxylate, 1,3,5-benzenetricarboxylate, 2,6-naphthalenedicarboxylate] are fabricated on ZnO micronanoarrays. These hybrid luminescent coatings of Tb(iii)@CPs/ZnO (Tb(iii) functionalized CP/ZnO) are prepared by solvothermal synthesis and a postsynthetic functionalization (PSF) approach. Tb(iii)@MOF-5/ZnO exhibits a highly detectable luminescence response for acetone molecules, and its structure, composition and morphology are characterized by XRD, EDS, ICP and SEM, respectively. It is first demonstrated that a lanthanide ion functionalized hybrid micronano-CP/ZnO coating is used as a small molecule sensor successfully. © 2016 The Royal Society of Chemistry.
| Original language | English |
|---|---|
| Pages (from-to) | 8466-8472 |
| Journal | Journal of Materials Chemistry C |
| Volume | 4 |
| Issue number | 36 |
| DOIs | |
| Publication status | Published - 2016 |
| Externally published | Yes |
Bibliographical note
Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].Funding
The authors acknowledge the financial support of the National Natural Science Foundation of China (51472275, 20973203 and 91022012) and Guangdong Natural Science Foundation (2014A030313207).
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