Tackling poison and leach: Catalysis by dangling thiol-palladium functions within a porous metal-organic solid

Bo Gui; Ka-Kit Yee; Yan-Lung Wong; Shek-Man Yiu; Matthias Zeller; Cheng Wang; Zhengta Xu

doi:10.1039/c5cc00140d

Tackling poison and leach: Catalysis by dangling thiol-palladium functions within a porous metal-organic solid

Bo Gui, Ka-Kit Yee, Yan-Lung Wong, Shek-Man Yiu, Matthias Zeller, Cheng Wang^*, Zhengta Xu^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

67 Citations (Scopus)

Abstract

Self-standing thiol (-SH) groups within a Zr(iv)-based metal-organic framework (MOF) anchor Pd(ii) atoms for catalytic applications: the spatial constraint prevents the thiol groups from sealing off/poisoning the Pd(ii) center, while the strong Pd-S bond precludes Pd leaching, enabling multiple cycles of heterogeneous catalysis to be executed. This journal is

Original language	English
Pages (from-to)	6917-6920
Journal	Chemical Communications
Volume	51
Issue number	32
Online published	27 Feb 2015
DOIs	https://doi.org/10.1039/c5cc00140d
Publication status	Published - 25 Apr 2015

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AU - Gui, Bo

AU - Yee, Ka-Kit

AU - Wong, Yan-Lung

AU - Yiu, Shek-Man

AU - Zeller, Matthias

AU - Wang, Cheng

AU - Xu, Zhengta

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AB - Self-standing thiol (-SH) groups within a Zr(iv)-based metal-organic framework (MOF) anchor Pd(ii) atoms for catalytic applications: the spatial constraint prevents the thiol groups from sealing off/poisoning the Pd(ii) center, while the strong Pd-S bond precludes Pd leaching, enabling multiple cycles of heterogeneous catalysis to be executed. This journal is

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JO - Chemical Communications

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Tackling poison and leach: Catalysis by dangling thiol-palladium functions within a porous metal-organic solid

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Correction: Tackling poison and leach: Catalysis by dangling thiol-palladium functions within a porous metal-organic solid Chemical Communications (2015) DOI 10.1039/c5cc00140d)

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