Tackling poison and leach : Catalysis by dangling thiol-palladium functions within a porous metal-organic solid

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal

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Author(s)

  • Bo Gui
  • Ka-Kit Yee
  • Shek-Man Yiu
  • Matthias Zeller
  • Cheng Wang

Detail(s)

Original languageEnglish
Pages (from-to)6917-6920
Journal / PublicationChemical Communications
Volume51
Issue number32
Online published27 Feb 2015
Publication statusPublished - 25 Apr 2015

Abstract

Self-standing thiol (-SH) groups within a Zr(iv)-based metal-organic framework (MOF) anchor Pd(ii) atoms for catalytic applications: the spatial constraint prevents the thiol groups from sealing off/poisoning the Pd(ii) center, while the strong Pd-S bond precludes Pd leaching, enabling multiple cycles of heterogeneous catalysis to be executed. This journal is

Citation Format(s)

Tackling poison and leach : Catalysis by dangling thiol-palladium functions within a porous metal-organic solid. / Gui, Bo; Yee, Ka-Kit; Wong, Yan-Lung; Yiu, Shek-Man; Zeller, Matthias; Wang, Cheng; Xu, Zhengta.

In: Chemical Communications, Vol. 51, No. 32, 25.04.2015, p. 6917-6920.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal