TY - JOUR
T1 - Synthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands
AU - Yam, V. W W
AU - Chu, B. W K
AU - Ko, C. C.
AU - Cheung, K. K.
PY - 2001
Y1 - 2001
N2 - A series of ruthenium(II) orthometallated aminocarbene complexes have been synthesized and characterized. Their electrochemistry, electronic absorption, emission, and the crystal structures of [Ru(phen)2{=C(CH2Ph)NHC6H4}]CF 3SO3, [Ru(bpy)2{=C(CH2Ph)NMeC6H4}]PF 6 and [Ru(bpy)2{=C(CH2C4H3S)NHC 6H4}]CF3SO3 have been studied. The nature of the electronic transitions and the origin of the emission are discussed and an assignment of a 3MLCT emission has been supported by EHMO studies.
AB - A series of ruthenium(II) orthometallated aminocarbene complexes have been synthesized and characterized. Their electrochemistry, electronic absorption, emission, and the crystal structures of [Ru(phen)2{=C(CH2Ph)NHC6H4}]CF 3SO3, [Ru(bpy)2{=C(CH2Ph)NMeC6H4}]PF 6 and [Ru(bpy)2{=C(CH2C4H3S)NHC 6H4}]CF3SO3 have been studied. The nature of the electronic transitions and the origin of the emission are discussed and an assignment of a 3MLCT emission has been supported by EHMO studies.
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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0034743192&origin=recordpage
M3 - RGC 22 - Publication in policy or professional journal
SN - 1470-479X
SP - 1911
EP - 1919
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 12
ER -