Synthesis, structure, and oxidative additions of a fluorous analogue of Vaska's complex, trans-[IrCl(CO){P[CH2 CH2(CF2) 5CF3]3}2]-altered reactivity in fluorocarbons and implications for catalysis
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 1612-1615 |
| Journal / Publication | Angewandte Chemie - International Edition in English |
| Volume | 36 |
| Issue number | 15 |
| Publication status | Published - 1997 |
| Externally published | Yes |
Link(s)
Abstract
The most highly fluorinated aliphatic species crystallized to date is 1 an exceptionally interesting molecule with regard to its structure and from a mechanistic standpoint. Four of the fluoroalkyl groups form raftlike domains, which pack back-to-back in a motif that maximizes parallel chains (depicted on the right). Complex 1 and CH3I react by a free radical chain mechanism in CF3C6F11, as opposed to the polar pathway for Vaska's complex in organic solvents. Although O2 is highly soluble in CF3C6F11, its addition to 1 is slower than in common organic solvents.
Research Area(s)
- Iridium, Ligand effects, O-O activation, Radical reactions, Two-phase catalysis
Citation Format(s)
Synthesis, structure, and oxidative additions of a fluorous analogue of Vaska's complex, trans-[IrCl(CO){P[CH2 CH2(CF2) 5CF3]3}2]-altered reactivity in fluorocarbons and implications for catalysis. / Guillevic, M. A.; Arif, A. M.; Horvath, I. T. et al.
In: Angewandte Chemie - International Edition in English, Vol. 36, No. 15, 1997, p. 1612-1615.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
