Synthesis, photophysical and electrochemincal properties of luminescent dinuclear copper(I) diimines

Vivian Wing-Wah Yam; Kenneth Kam-Wing Lo

doi:10.1039/DT9950000499

Synthesis, photophysical and electrochemincal properties of luminescent dinuclear copper(I) diimines

Vivian Wing-Wah Yam, Kenneth Kam-Wing Lo

Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal

30 Citations (Scopus)

Abstract

Reaction of [Cu(PPh₃)₂(MeCN)₂]BF₄ with bridging diimine ligands (L) in CH₂Cl₂ gave dinuclear copper(I) complexes [{Cu(PPh₃)₂}₂L]²⁺ [L = 2,3-bis(2-pyridyl)pyrazine, 6,7-dimethyl-2,3-bis(2-pyridyl)quinoxaline, 2,3-bis(2-pyridyl) quinoxaline, 6,7-dichloro-2,3-bis(2-pyridyl)quinoxaline or 2,3-bis(2-pyridyl)benzo[g] quinoxaline], which exhibit rich photophysical and electrochemical properties.

Original language	English
Pages (from-to)	499-500
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	3
DOIs	https://doi.org/10.1039/DT9950000499
Publication status	Published - 1995
Externally published	Yes

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@article{60626b368fb84471a57dfaf37b08afb8,

title = "Synthesis, photophysical and electrochemincal properties of luminescent dinuclear copper(I) diimines",

abstract = "Reaction of [Cu(PPh3)2(MeCN)2]BF4 with bridging diimine ligands (L) in CH2Cl2 gave dinuclear copper(I) complexes [{Cu(PPh3)2}2L]2+ [L = 2,3-bis(2-pyridyl)pyrazine, 6,7-dimethyl-2,3-bis(2-pyridyl)quinoxaline, 2,3-bis(2-pyridyl) quinoxaline, 6,7-dichloro-2,3-bis(2-pyridyl)quinoxaline or 2,3-bis(2-pyridyl)benzo[g] quinoxaline], which exhibit rich photophysical and electrochemical properties.",

author = "Yam, {Vivian Wing-Wah} and Lo, {Kenneth Kam-Wing}",

year = "1995",

doi = "10.1039/DT9950000499",

language = "English",

pages = "499--500",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "3",

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TY - JOUR

T1 - Synthesis, photophysical and electrochemincal properties of luminescent dinuclear copper(I) diimines

AU - Yam, Vivian Wing-Wah

AU - Lo, Kenneth Kam-Wing

PY - 1995

Y1 - 1995

N2 - Reaction of [Cu(PPh3)2(MeCN)2]BF4 with bridging diimine ligands (L) in CH2Cl2 gave dinuclear copper(I) complexes [{Cu(PPh3)2}2L]2+ [L = 2,3-bis(2-pyridyl)pyrazine, 6,7-dimethyl-2,3-bis(2-pyridyl)quinoxaline, 2,3-bis(2-pyridyl) quinoxaline, 6,7-dichloro-2,3-bis(2-pyridyl)quinoxaline or 2,3-bis(2-pyridyl)benzo[g] quinoxaline], which exhibit rich photophysical and electrochemical properties.

AB - Reaction of [Cu(PPh3)2(MeCN)2]BF4 with bridging diimine ligands (L) in CH2Cl2 gave dinuclear copper(I) complexes [{Cu(PPh3)2}2L]2+ [L = 2,3-bis(2-pyridyl)pyrazine, 6,7-dimethyl-2,3-bis(2-pyridyl)quinoxaline, 2,3-bis(2-pyridyl) quinoxaline, 6,7-dichloro-2,3-bis(2-pyridyl)quinoxaline or 2,3-bis(2-pyridyl)benzo[g] quinoxaline], which exhibit rich photophysical and electrochemical properties.

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-37049080228&origin=recordpage

U2 - 10.1039/DT9950000499

DO - 10.1039/DT9950000499

M3 - RGC 22 - Publication in policy or professional journal

SN - 1470-479X

SP - 499

EP - 500

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 3

ER -

Synthesis, photophysical and electrochemincal properties of luminescent dinuclear copper(I) diimines

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