Synthesis of Polyaza Macrocyclic Ligands Incorporating Pyridine Units

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

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Author(s)

Detail(s)

Original languageEnglish
Pages (from-to)1066-1077
Journal / PublicationHelvetica Chimica Acta
Volume72
Issue number5
Publication statusPublished - 9 Aug 1989
Externally publishedYes

Abstract

The synthesis of nine macrocyclic polyamines 2‐10 containing pyridine units is described. These compounds are 22‐ (9), 24‐ (2‐4,6,8,10), or 26‐ (5, 7) membered hexaaza (2,3,9,10) or octaaza (4–7) macrocycles in which one to four pyridine units are incorporated. Compounds 3,4,9, and 10 are homoditopic ligands, whereas 2 and 5 are heteroditopic and 6−8 multitopic receptors. Compounds 2‐10 are potential ligands for metal cations as well as, in their protonated forms, for anions. Protonated macrocycles 2−10 are also potential catalysts for the hydrolysis of nucleotides and polyphosphates. Copyright © 1989 Verlag GmbH & Co. KGaA, Weinheim

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Citation Format(s)

Synthesis of Polyaza Macrocyclic Ligands Incorporating Pyridine Units. / Hosseini, Mir Wais; Comarmond, Jacques; Lehn, Jean‐Marie.
In: Helvetica Chimica Acta, Vol. 72, No. 5, 09.08.1989, p. 1066-1077.

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review