Abstract
The synthesis of nine macrocyclic polyamines 2‐10 containing pyridine units is described. These compounds are 22‐ (9), 24‐ (2‐4,6,8,10), or 26‐ (5, 7) membered hexaaza (2,3,9,10) or octaaza (4–7) macrocycles in which one to four pyridine units are incorporated. Compounds 3,4,9, and 10 are homoditopic ligands, whereas 2 and 5 are heteroditopic and 6−8 multitopic receptors. Compounds 2‐10 are potential ligands for metal cations as well as, in their protonated forms, for anions. Protonated macrocycles 2−10 are also potential catalysts for the hydrolysis of nucleotides and polyphosphates. Copyright © 1989 Verlag GmbH & Co. KGaA, Weinheim
| Original language | English |
|---|---|
| Pages (from-to) | 1066-1077 |
| Journal | Helvetica Chimica Acta |
| Volume | 72 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 9 Aug 1989 |
| Externally published | Yes |
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