Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H2S. Synthesis and crystal and molecular structure of H2Os5(CO)14(μ3-S)2

Richard D. Adams; István T. Horváth; Li-Wu Yang

doi:10.1021/om50003a036

Author(s)

Richard D. Adams
István T. Horváth
Li-Wu Yang

Detail(s)

Original language	English
Pages (from-to)	1257-1258
Journal / Publication	Organometallics
Volume	2
Issue number	9
Publication status	Published - 1983
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1021/om50003a036 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-0010960461&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(f2aab68b-a424-4984-9fde-73f1bfd42dfa).html

Abstract

The reactions of the closo-sulfido osmium carbonyl cluster compounds Os₄(CO)₁₂(μ₃-S), I, and Os₅(CO)₁₅(μ₄-S), II, with H₂S yield the open cluster compounds H₂Os₄(CO)₁₂(μ₃-S)₂, III, and H₂Os₅(CO)₁₄(μ₃-S)₂, IV, in yields of 55% and 94%, respectively. In each reaction one H₂S molecule has been converted into a triply bridging sulfido ligand and two hydride ligands. © 1983 American Chemical Society.

Citation Format(s)

[ RIS ] [ BibTeX ]

Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H₂S. Synthesis and crystal and molecular structure of H₂Os₅(CO)₁₄(μ₃-S)₂. / Adams, Richard D.; Horváth, István T.; Yang, Li-Wu.
In: Organometallics, Vol. 2, No. 9, 1983, p. 1257-1258.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Adams, RD, Horváth, IT & Yang, L-W 1983, 'Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H₂S. Synthesis and crystal and molecular structure of H₂Os₅(CO)₁₄(μ₃-S)₂', Organometallics, vol. 2, no. 9, pp. 1257-1258. https://doi.org/10.1021/om50003a036

Adams, R. D., Horváth, I. T., & Yang, L.-W. (1983). Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H₂S. Synthesis and crystal and molecular structure of H₂Os₅(CO)₁₄(μ₃-S)₂. Organometallics, 2(9), 1257-1258. https://doi.org/10.1021/om50003a036

Adams RD, Horváth IT, Yang LW. Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H₂S. Synthesis and crystal and molecular structure of H₂Os₅(CO)₁₄(μ₃-S)₂. Organometallics. 1983;2(9):1257-1258. doi: 10.1021/om50003a036

Adams, Richard D. ; Horváth, István T. ; Yang, Li-Wu. / Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H₂S. Synthesis and crystal and molecular structure of H₂Os₅(CO)₁₄(μ₃-S)₂. In: Organometallics. 1983 ; Vol. 2, No. 9. pp. 1257-1258.