Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H2S. Synthesis and crystal and molecular structure of H2Os5(CO)14(μ3-S)2

Richard D. Adams; István T. Horváth; Li-Wu Yang

doi:10.1021/om50003a036

Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H₂S. Synthesis and crystal and molecular structure of H₂Os₅(CO)₁₄(μ₃-S)₂

Richard D. Adams
, István T. Horváth
, Li-Wu Yang

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

15 Citations (Scopus)

Abstract

The reactions of the closo-sulfido osmium carbonyl cluster compounds Os₄(CO)₁₂(μ₃-S), I, and Os₅(CO)₁₅(μ₄-S), II, with H₂S yield the open cluster compounds H₂Os₄(CO)₁₂(μ₃-S)₂, III, and H₂Os₅(CO)₁₄(μ₃-S)₂, IV, in yields of 55% and 94%, respectively. In each reaction one H₂S molecule has been converted into a triply bridging sulfido ligand and two hydride ligands. © 1983 American Chemical Society.

Original language	English
Pages (from-to)	1257-1258
Journal	Organometallics
Volume	2
Issue number	9
DOIs	https://doi.org/10.1021/om50003a036
Publication status	Published - 1983
Externally published	Yes

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@article{f2aab68ba42449849fde73f1bfd42dfa,

title = "Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H2S. Synthesis and crystal and molecular structure of H2Os5(CO)14(μ3-S)2",

abstract = "The reactions of the closo-sulfido osmium carbonyl cluster compounds Os4(CO)12(μ3-S), I, and Os5(CO)15(μ4-S), II, with H2S yield the open cluster compounds H2Os4(CO)12(μ3-S)2, III, and H2Os5(CO)14(μ3-S)2, IV, in yields of 55\% and 94\%, respectively. In each reaction one H2S molecule has been converted into a triply bridging sulfido ligand and two hydride ligands. {\textcopyright} 1983 American Chemical Society.",

author = "Adams, \{Richard D.\} and Horv{\'a}th, \{Istv{\'a}n T.\} and Li-Wu Yang",

year = "1983",

doi = "10.1021/om50003a036",

language = "English",

volume = "2",

pages = "1257--1258",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "9",

}

Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H₂S. Synthesis and crystal and molecular structure of H₂Os₅(CO)₁₄(μ₃-S)₂. / Adams, Richard D.; Horváth, István T.; Yang, Li-Wu.
In: Organometallics, Vol. 2, No. 9, 1983, p. 1257-1258.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with H2S. Synthesis and crystal and molecular structure of H2Os5(CO)14(μ3-S)2

AU - Adams, Richard D.

AU - Horváth, István T.

AU - Yang, Li-Wu

PY - 1983

Y1 - 1983

N2 - The reactions of the closo-sulfido osmium carbonyl cluster compounds Os4(CO)12(μ3-S), I, and Os5(CO)15(μ4-S), II, with H2S yield the open cluster compounds H2Os4(CO)12(μ3-S)2, III, and H2Os5(CO)14(μ3-S)2, IV, in yields of 55% and 94%, respectively. In each reaction one H2S molecule has been converted into a triply bridging sulfido ligand and two hydride ligands. © 1983 American Chemical Society.

AB - The reactions of the closo-sulfido osmium carbonyl cluster compounds Os4(CO)12(μ3-S), I, and Os5(CO)15(μ4-S), II, with H2S yield the open cluster compounds H2Os4(CO)12(μ3-S)2, III, and H2Os5(CO)14(μ3-S)2, IV, in yields of 55% and 94%, respectively. In each reaction one H2S molecule has been converted into a triply bridging sulfido ligand and two hydride ligands. © 1983 American Chemical Society.

UR - https://www.scopus.com/pages/publications/0010960461

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0010960461&origin=recordpage

U2 - 10.1021/om50003a036

DO - 10.1021/om50003a036

M3 - RGC 21 - Publication in refereed journal

SN - 0276-7333

VL - 2

SP - 1257

EP - 1258

JO - Organometallics

JF - Organometallics

IS - 9

ER -