Synthesis of Macrobicyclic Polyamines by Direct Macrobicyclisation via Tripode‐Tripode Coupling

Bernard Dietrich; Mir Wais Hosseini; Jean‐Marie Lehn; Richard B. Sessions

doi:10.1002/hlca.19850680202

Synthesis of Macrobicyclic Polyamines by Direct Macrobicyclisation via Tripode‐Tripode Coupling

Bernard Dietrich
, Mir Wais Hosseini
, Jean‐Marie Lehn
, Richard B. Sessions

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

91 Citations (Scopus)

Abstract

The synthesis of five macrobicyclic polyamines 1–5 is described following a route in which the macrobicycle is formed by the coupling of two tripodal subunits. Such a sequence is appreciably shorter than the stepwise construction via a macrocycle, and may give higher yields, as illustrated by the case of bis‐tren 3, which has been synthesized following both routes. Copyright © 1985 Verlag GmbH & Co. KGaA, Weinheim

Original language	English
Pages (from-to)	289-299
Journal	Helvetica Chimica Acta
Volume	68
Issue number	2
DOIs	https://doi.org/10.1002/hlca.19850680202
Publication status	Published - 27 Mar 1985
Externally published	Yes

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Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

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title = "Synthesis of Macrobicyclic Polyamines by Direct Macrobicyclisation via Tripode‐Tripode Coupling",

abstract = "The synthesis of five macrobicyclic polyamines 1–5 is described following a route in which the macrobicycle is formed by the coupling of two tripodal subunits. Such a sequence is appreciably shorter than the stepwise construction via a macrocycle, and may give higher yields, as illustrated by the case of bis‐tren 3, which has been synthesized following both routes. Copyright {\textcopyright} 1985 Verlag GmbH \& Co. KGaA, Weinheim",

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AU - Dietrich, Bernard

AU - Hosseini, Mir Wais

AU - Lehn, Jean‐Marie

AU - Sessions, Richard B.

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 1985/3/27

Y1 - 1985/3/27

N2 - The synthesis of five macrobicyclic polyamines 1–5 is described following a route in which the macrobicycle is formed by the coupling of two tripodal subunits. Such a sequence is appreciably shorter than the stepwise construction via a macrocycle, and may give higher yields, as illustrated by the case of bis‐tren 3, which has been synthesized following both routes. Copyright © 1985 Verlag GmbH & Co. KGaA, Weinheim

AB - The synthesis of five macrobicyclic polyamines 1–5 is described following a route in which the macrobicycle is formed by the coupling of two tripodal subunits. Such a sequence is appreciably shorter than the stepwise construction via a macrocycle, and may give higher yields, as illustrated by the case of bis‐tren 3, which has been synthesized following both routes. Copyright © 1985 Verlag GmbH & Co. KGaA, Weinheim

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U2 - 10.1002/hlca.19850680202

DO - 10.1002/hlca.19850680202

M3 - RGC 21 - Publication in refereed journal

SN - 0018-019X

VL - 68

SP - 289

EP - 299

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 2

ER -

Synthesis of Macrobicyclic Polyamines by Direct Macrobicyclisation via Tripode‐Tripode Coupling

Abstract

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