Synthesis of LiFe_1-xNi_xPO₄/C composites and their electrochemical performance

LiFePO₄/C and LiFe_1-xNi_xPO₄/C (x = 0, 0.02, 0.04, and 0.06) composites were prepared using solid-state reaction. The as-prepared composites were characterized by using X-ray diffraction, charge-discharge cycling, cyclic voltammograms, Raman spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and other techniques. The experimental results show that all as-prepared composites have a single phase of orthorhombic olivine-type structure with the Pnmb space group. The as-prepared LiFe_1-xNi_xPO₄/C composites exhibit high capacities and good cycling performance; e.g., the LiFe_0.98Ni_0.02PO₄/C composite delivers 142 and 138 mAh g^-1 at the 0.1 C rate for the first and fifth cycles, respectively. Such composites also show good rate capabilities; e.g., when discharged at the 2 C rate the LiFe_0.98Ni_0.02PO₄/C composite delivers an initial capacity of 121 mAh g^-1, 85% of the discharge capacity at the 0.1 C rate. The reason why the LiFe_1-xNi_xPO₄/C composites have better electrochemical performance compared to the LiFePO₄/C composites is because nickel doping enhances the P{single bond}O bond, stabilizes the structure, and thus the charge-transfer resistance and cathode particle resistance of the composites are decreased. Crown Copyright © 2009.