Synthesis of Carbon Doped TiO2 Quantum Dots for Photocatalytic Sterilization under the Visible Light Irradiation and the Mechanisms

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Original languageEnglish
Article number01013
Journal / PublicationE3S Web of Conferences
Volume118
Online published4 Oct 2019
Publication statusPublished - 2019

Conference

Title2019 4th International Conference on Advances in Energy and Environment Research (ICAEER 2019)
LocationShanghai University of Electric Power
PlaceChina
CityShanghai
Period16 - 18 August 2019

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Abstract

In this article, the carbon doped TiO2 (C-TiO2) quantum dots (QDs) were prepared through the hydrothermal method and calcination. The size of the C-TiO2 QDs is about 5.7 nm. The doping amount of carbon can be tuned by adjusting the volumes of the carbon source, ethylene glycol added. The carbon atoms are proved to be doped into the interstitial sites of TiO2 lattice and induce the change of chemical states of Ti 2p and C 1s. The doping of carbon leads to the increasing photocatalytic sterilization of E. coli under the visible light irradiation. The survival rate of E. coli cells over C-TiO2 is only 1.5 % after 6 h. The reactive oxygen species (ROS), such as hydroxyl radical and superoxide radical, are considered as the primary factors for the photocatalytic sterilization. Due to oxidative stress of the attack by ROS, the enzyme activity per cells increases for self-protection during the photocatalytic sterilization.

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