Synthesis, crystal structures, and magnetic properties of heterodimetallic Ruiii-3D coordination compounds based on a meridional tricyanoruthenium(III) building block

Jing Xiang; Li-Hui Jia; Hui-Sheng Wang; Shie-Ming Peng; Song Gao; Tai-Chu Lau

doi:10.1002/ejic.201402959

Synthesis, crystal structures, and magnetic properties of heterodimetallic Ruⁱⁱⁱ-3D coordination compounds based on a meridional tricyanoruthenium(III) building block

Jing Xiang^*
, Li-Hui Jia
, Hui-Sheng Wang
, Shie-Ming Peng
, Song Gao
, Tai-Chu Lau^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

10 Citations (Scopus)

Abstract

The synthesis, crystal structures, and magnetic properties of three cyano-bridged heterodimetallic compounds prepared from the paramagnetic Ru^III building block mer-[Ru^III(CN-sap)(CN)₃]^2- (1) are described. Complex 1 reacts with [Mn^II(L^N5)(Cl)(H₂O)]Cl and [Mn^II(bipy)₂(Cl)₂] (bipy = bipyridine) to produce the 1D zigzag chain {[Ru^III(CN-sap)(CN)](μ-CN)₂[Mn^II(L^N5)]·3MeOH}_n {2; L^N5 = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene, CN-sapH₂ = 2-hydroxy-N-(2-hydroxyphenyl)benzimidoyl cyanide} and the octanuclear compound {[Ru^III(CN-sap)(CN)](μ-CN)₂[Mn^II(bipy)(MeOH)][Ru^III(CN-sap)](μ-CN)₃[Mn^II(bipy)₂]}₂·8MeOH (3), respectively. The Mn^II centers have a pentagonal-bipyramidal environment in 2 and a distorted octahedral environment in 3. Complex 1 reacts with [Ni^II(cyclen)(Cl)₂] (cyclen = 1,4,7,10-tetraazacyclododecane) in MeOH to produce the molecular square {[Ru^III(CN-sap)(CN)](μ-CN)₂[Ni^II(cyclen)]}₂·8MeOH (4). Compounds 2 and 3 exhibit antiferromagnetic coupling between the Ru^III and Mn^II centers, whereas 4 exhibits ferromagnetic coupling between the Ru^III and Ni^II centers through the cyano bridges.

Original language	English
Pages (from-to)	1065-1073
Journal	European Journal of Inorganic Chemistry
Volume	2015
Issue number	6
DOIs	https://doi.org/10.1002/ejic.201402959
Publication status	Published - Feb 2015

Research Keywords

Cyanides
Heterometallic complexes
Magnetic properties
Ruthenium

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@article{bf8019e9171d454d96b6cfaebbe3385c,

title = "Synthesis, crystal structures, and magnetic properties of heterodimetallic Ruiii-3D coordination compounds based on a meridional tricyanoruthenium(III) building block",

abstract = "The synthesis, crystal structures, and magnetic properties of three cyano-bridged heterodimetallic compounds prepared from the paramagnetic RuIII building block mer-[RuIII(CN-sap)(CN)3]2- (1) are described. Complex 1 reacts with [MnII(LN5)(Cl)(H2O)]Cl and [MnII(bipy)2(Cl)2] (bipy = bipyridine) to produce the 1D zigzag chain \{[RuIII(CN-sap)(CN)](μ-CN)2[MnII(LN5)]·3MeOH\}n \{2; LN5 = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene, CN-sapH2 = 2-hydroxy-N-(2-hydroxyphenyl)benzimidoyl cyanide\} and the octanuclear compound \{[RuIII(CN-sap)(CN)](μ-CN)2[MnII(bipy)(MeOH)][RuIII(CN-sap)](μ-CN)3[MnII(bipy)2]\}2·8MeOH (3), respectively. The MnII centers have a pentagonal-bipyramidal environment in 2 and a distorted octahedral environment in 3. Complex 1 reacts with [NiII(cyclen)(Cl)2] (cyclen = 1,4,7,10-tetraazacyclododecane) in MeOH to produce the molecular square \{[RuIII(CN-sap)(CN)](μ-CN)2[NiII(cyclen)]\}2·8MeOH (4). Compounds 2 and 3 exhibit antiferromagnetic coupling between the RuIII and MnII centers, whereas 4 exhibits ferromagnetic coupling between the RuIII and NiII centers through the cyano bridges.",

keywords = "Cyanides, Heterometallic complexes, Magnetic properties, Ruthenium",

author = "Jing Xiang and Li-Hui Jia and Hui-Sheng Wang and Shie-Ming Peng and Song Gao and Tai-Chu Lau",

year = "2015",

month = feb,

doi = "10.1002/ejic.201402959",

language = "English",

volume = "2015",

pages = "1065--1073",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag GmbH",

number = "6",

}

Synthesis, crystal structures, and magnetic properties of heterodimetallic Ruⁱⁱⁱ-3D coordination compounds based on a meridional tricyanoruthenium(III) building block. / Xiang, Jing; Jia, Li-Hui; Wang, Hui-Sheng et al.
In: European Journal of Inorganic Chemistry, Vol. 2015, No. 6, 02.2015, p. 1065-1073.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Synthesis, crystal structures, and magnetic properties of heterodimetallic Ruiii-3D coordination compounds based on a meridional tricyanoruthenium(III) building block

AU - Xiang, Jing

AU - Jia, Li-Hui

AU - Wang, Hui-Sheng

AU - Peng, Shie-Ming

AU - Gao, Song

AU - Lau, Tai-Chu

PY - 2015/2

Y1 - 2015/2

N2 - The synthesis, crystal structures, and magnetic properties of three cyano-bridged heterodimetallic compounds prepared from the paramagnetic RuIII building block mer-[RuIII(CN-sap)(CN)3]2- (1) are described. Complex 1 reacts with [MnII(LN5)(Cl)(H2O)]Cl and [MnII(bipy)2(Cl)2] (bipy = bipyridine) to produce the 1D zigzag chain {[RuIII(CN-sap)(CN)](μ-CN)2[MnII(LN5)]·3MeOH}n {2; LN5 = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene, CN-sapH2 = 2-hydroxy-N-(2-hydroxyphenyl)benzimidoyl cyanide} and the octanuclear compound {[RuIII(CN-sap)(CN)](μ-CN)2[MnII(bipy)(MeOH)][RuIII(CN-sap)](μ-CN)3[MnII(bipy)2]}2·8MeOH (3), respectively. The MnII centers have a pentagonal-bipyramidal environment in 2 and a distorted octahedral environment in 3. Complex 1 reacts with [NiII(cyclen)(Cl)2] (cyclen = 1,4,7,10-tetraazacyclododecane) in MeOH to produce the molecular square {[RuIII(CN-sap)(CN)](μ-CN)2[NiII(cyclen)]}2·8MeOH (4). Compounds 2 and 3 exhibit antiferromagnetic coupling between the RuIII and MnII centers, whereas 4 exhibits ferromagnetic coupling between the RuIII and NiII centers through the cyano bridges.

AB - The synthesis, crystal structures, and magnetic properties of three cyano-bridged heterodimetallic compounds prepared from the paramagnetic RuIII building block mer-[RuIII(CN-sap)(CN)3]2- (1) are described. Complex 1 reacts with [MnII(LN5)(Cl)(H2O)]Cl and [MnII(bipy)2(Cl)2] (bipy = bipyridine) to produce the 1D zigzag chain {[RuIII(CN-sap)(CN)](μ-CN)2[MnII(LN5)]·3MeOH}n {2; LN5 = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene, CN-sapH2 = 2-hydroxy-N-(2-hydroxyphenyl)benzimidoyl cyanide} and the octanuclear compound {[RuIII(CN-sap)(CN)](μ-CN)2[MnII(bipy)(MeOH)][RuIII(CN-sap)](μ-CN)3[MnII(bipy)2]}2·8MeOH (3), respectively. The MnII centers have a pentagonal-bipyramidal environment in 2 and a distorted octahedral environment in 3. Complex 1 reacts with [NiII(cyclen)(Cl)2] (cyclen = 1,4,7,10-tetraazacyclododecane) in MeOH to produce the molecular square {[RuIII(CN-sap)(CN)](μ-CN)2[NiII(cyclen)]}2·8MeOH (4). Compounds 2 and 3 exhibit antiferromagnetic coupling between the RuIII and MnII centers, whereas 4 exhibits ferromagnetic coupling between the RuIII and NiII centers through the cyano bridges.

KW - Cyanides

KW - Heterometallic complexes

KW - Magnetic properties

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/84923233835

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84923233835&origin=recordpage

U2 - 10.1002/ejic.201402959

DO - 10.1002/ejic.201402959

M3 - RGC 21 - Publication in refereed journal

SN - 1434-1948

VL - 2015

SP - 1065

EP - 1073

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 6

ER -