Synthesis, crystal structures, and luminescence of organic-lanthanide complexes with nicotinate and isonicotinate ligands

Guohua Jia; Ga-Lai Law; Ka-Leung Wong; Peter A. Tanner; Wing-Tak Wong

doi:10.1021/ic8010103

Author(s)

Guohua Jia
Ga-Lai Law
Ka-Leung Wong
Peter A. Tanner
Wing-Tak Wong

Detail(s)

Original language	English
Pages (from-to)	9431-9438
Journal / Publication	Inorganic Chemistry
Volume	47
Issue number	20
Publication status	Published - 20 Oct 2008

Link(s)

DOI	DOI https://doi.org/10.1021/ic8010103 Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-55249114408&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(c195d449-6d9a-4276-90be-df136c43df2b).html

Abstract

Six lanthanide coordination compounds with two isomeric carboxylic acids, nicotinic acid (HL¹) and isonicotinic acid (HL²), [(L ¹)₃Ln(H₂O)₂]₂ (Ln = Eu, 1; Gd, 2; Tb, 3) and [(L²)₂Ln(H₂O) ₄][NO₃] (Ln = Eu, 4; Gd, 5; Tb, 6), have been synthesized and structurally characterized by single-crystal X-ray diffraction. Complexes 1-3 are dimeric whereas 4-6 are polymeric, all with 8-coordination of Ln ³⁺. The distinction between these lanthanide complexes is readily accomplished from the 10 K high resolution electronic emission spectra. Spectral interpretation is given for the Eu³⁺ complexes 1, 4, whereas the spectra of 3 and 6 are more complex. The relationships between spectroscopic and crystallographic site symmetries are discussed. The calculated second rank crystal field strengths of Eu³⁺ in 1 and 4 are intermediate in magnitude. © 2008 American Chemical Society.

Citation Format(s)

[ RIS ] [ BibTeX ]

Synthesis, crystal structures, and luminescence of organic-lanthanide complexes with nicotinate and isonicotinate ligands. / Jia, Guohua; Law, Ga-Lai; Wong, Ka-Leung et al.

In: Inorganic Chemistry, Vol. 47, No. 20, 20.10.2008, p. 9431-9438.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Jia, G, Law, G-L, Wong, K-L, Tanner, PA & Wong, W-T 2008, 'Synthesis, crystal structures, and luminescence of organic-lanthanide complexes with nicotinate and isonicotinate ligands', Inorganic Chemistry, vol. 47, no. 20, pp. 9431-9438. https://doi.org/10.1021/ic8010103

Jia, G., Law, G-L., Wong, K-L., Tanner, P. A., & Wong, W-T. (2008). Synthesis, crystal structures, and luminescence of organic-lanthanide complexes with nicotinate and isonicotinate ligands. Inorganic Chemistry, 47(20), 9431-9438. https://doi.org/10.1021/ic8010103

Jia G, Law G-L, Wong K-L, Tanner PA, Wong W-T. Synthesis, crystal structures, and luminescence of organic-lanthanide complexes with nicotinate and isonicotinate ligands. Inorganic Chemistry. 2008 Oct 20;47(20):9431-9438. doi: 10.1021/ic8010103

Jia, Guohua ; Law, Ga-Lai ; Wong, Ka-Leung et al. / Synthesis, crystal structures, and luminescence of organic-lanthanide complexes with nicotinate and isonicotinate ligands. In: Inorganic Chemistry. 2008 ; Vol. 47, No. 20. pp. 9431-9438.