Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide: Hg7InS6Cl5

Yi Liu; Fengxia Wei; Sing Ning Yeo; Fu Min Lee; Christian Kloc; Qingyu Yan; Huey Hoon Hng; Jan Ma; Qichun Zhang

doi:10.1021/ic202746y

Author(s)

Yi Liu
Fengxia Wei
Sing Ning Yeo
Fu Min Lee
Christian Kloc
Qingyu Yan
Huey Hoon Hng
Jan Ma

Detail(s)

Original language	English
Pages (from-to)	4414-4416
Journal / Publication	Inorganic Chemistry
Volume	51
Issue number	8
Online published	29 Mar 2012
Publication status	Published - 16 Apr 2012
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1021/ic202746y Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-84859798646&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(9c636a9b-5883-441e-a829-e3d9ef39deec).html

Abstract

A crystalline three-dimensional (3D) quaternary chalcohalide, Hg₇InS₆Cl₅ (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg-IIIA-Q-X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV. © 2012 American Chemical Society.

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Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide: Hg₇InS₆Cl₅. / Liu, Yi; Wei, Fengxia; Yeo, Sing Ning et al.
In: Inorganic Chemistry, Vol. 51, No. 8, 16.04.2012, p. 4414-4416.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Liu, Y, Wei, F, Yeo, SN, Lee, FM, Kloc, C, Yan, Q, Hng, HH, Ma, J & Zhang, Q 2012, 'Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide: Hg₇InS₆Cl₅', Inorganic Chemistry, vol. 51, no. 8, pp. 4414-4416. https://doi.org/10.1021/ic202746y

Liu, Y., Wei, F., Yeo, S. N., Lee, F. M., Kloc, C., Yan, Q., Hng, H. H., Ma, J., & Zhang, Q. (2012). Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide: Hg₇InS₆Cl₅. Inorganic Chemistry, 51(8), 4414-4416. https://doi.org/10.1021/ic202746y

Liu Y, Wei F, Yeo SN, Lee FM, Kloc C, Yan Q et al. Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide: Hg₇InS₆Cl₅. Inorganic Chemistry. 2012 Apr 16;51(8):4414-4416. Epub 2012 Mar 29. doi: 10.1021/ic202746y

Liu, Yi ; Wei, Fengxia ; Yeo, Sing Ning et al. / Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide : Hg₇InS₆Cl₅. In: Inorganic Chemistry. 2012 ; Vol. 51, No. 8. pp. 4414-4416.

Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide : Hg7InS6Cl5

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Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide : Hg₇InS₆Cl₅