Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide: Hg7InS6Cl5

Yi Liu; Fengxia Wei; Sing Ning Yeo; Fu Min Lee; Christian Kloc; Qingyu Yan; Huey Hoon Hng; Jan Ma; Qichun Zhang

doi:10.1021/ic202746y

Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide: Hg₇InS₆Cl₅

Yi Liu, Fengxia Wei, Sing Ning Yeo, Fu Min Lee, Christian Kloc, Qingyu Yan, Huey Hoon Hng, Jan Ma, Qichun Zhang^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

40 Citations (Scopus)

Abstract

A crystalline three-dimensional (3D) quaternary chalcohalide, Hg₇InS₆Cl₅ (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg-IIIA-Q-X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV. © 2012 American Chemical Society.

Original language	English
Pages (from-to)	4414-4416
Journal	Inorganic Chemistry
Volume	51
Issue number	8
Online published	29 Mar 2012
DOIs	https://doi.org/10.1021/ic202746y
Publication status	Published - 16 Apr 2012
Externally published	Yes

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@article{9c636a9b5883441ea829e3d9ef39deec,

title = "Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide: Hg7InS6Cl5",

abstract = "A crystalline three-dimensional (3D) quaternary chalcohalide, Hg7InS6Cl5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg-IIIA-Q-X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV. {\textcopyright} 2012 American Chemical Society.",

author = "Yi Liu and Fengxia Wei and Yeo, {Sing Ning} and Lee, {Fu Min} and Christian Kloc and Qingyu Yan and Hng, {Huey Hoon} and Jan Ma and Qichun Zhang",

year = "2012",

month = apr,

day = "16",

doi = "10.1021/ic202746y",

language = "English",

volume = "51",

pages = "4414--4416",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg-In-S-Cl Chalcohalide

T2 - Hg7InS6Cl5

AU - Liu, Yi

AU - Wei, Fengxia

AU - Yeo, Sing Ning

AU - Lee, Fu Min

AU - Kloc, Christian

AU - Yan, Qingyu

AU - Hng, Huey Hoon

AU - Ma, Jan

AU - Zhang, Qichun

PY - 2012/4/16

Y1 - 2012/4/16

N2 - A crystalline three-dimensional (3D) quaternary chalcohalide, Hg7InS6Cl5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg-IIIA-Q-X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV. © 2012 American Chemical Society.

AB - A crystalline three-dimensional (3D) quaternary chalcohalide, Hg7InS6Cl5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg-IIIA-Q-X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV. © 2012 American Chemical Society.

UR - http://www.scopus.com/inward/record.url?scp=84859798646&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84859798646&origin=recordpage

U2 - 10.1021/ic202746y

DO - 10.1021/ic202746y

M3 - RGC 21 - Publication in refereed journal

SN - 0020-1669

VL - 51

SP - 4414

EP - 4416

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 8

ER -