Synthesis, characterization, physical properties, and OLED application of single BN-fused perylene diimide
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 196-203 |
| Journal / Publication | Journal of Organic Chemistry |
| Volume | 80 |
| Issue number | 1 |
| Online published | 10 Dec 2014 |
| Publication status | Published - 2 Jan 2015 |
| Externally published | Yes |
Link(s)
Abstract
It is very challenging to introduce azaborine into an electrondeficient arene system because of unfavorable intramolecular electrophilic borylation reaction. In this report, we adopted a straightforward methodology to construct a large BN-embedded π-system based on perylene diimide (PDI), which is the first BN-annulation example with highly electron-withdrawing polycyclic aromatic hydrocarbons. The physical properties of the as-prepared N,N-dicyclohexyl-1-aza-12-bora-benzoperylene diimide (PDI-1BN) have been fully studied, and its sensing behavior to fluoride ion as well as its OLED performance was also investigated.
Citation Format(s)
Synthesis, characterization, physical properties, and OLED application of single BN-fused perylene diimide. / Li, Gang; Zhao, Yongbiao; Li, Junbo et al.
In: Journal of Organic Chemistry, Vol. 80, No. 1, 02.01.2015, p. 196-203.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
