Synthesis, Characterization, and Sensing Behavior of an N-heteropentacene

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

10 Scopus Citations
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Author(s)

Detail(s)

Original languageEnglish
Pages (from-to)203-208
Journal / PublicationAsian Journal of Organic Chemistry
Volume3
Issue number2
Online published11 Dec 2013
Publication statusPublished - Feb 2014
Externally publishedYes

Abstract

An N-heteropentacene, 1,2,5,6-tetra(5-hexylthiophene-2-yl)-hexaazapentacene (4HP), was synthesized through one-step cyclocondensation reaction. The binding behavior of 4HP toward various cations (Ca2+, Cd2+, Co2+, Cr2+, Cu2+ Fe3+, Hg2+, K+, Li+, Mg2+, Mn2+, Na+, Ni2+, Zn2+, and Pb2) was investigated by UV/vis and fluorescence spectroscopy. 4HP demonstrated a selective and sensitive response towards Cu2+ ion, and the detection limit reached 1.2μM in N,N-dimethylformamide solution. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Research Area(s)

  • Chemosensors, Copper, N-heteropentacenes, Oligoacenes, Organic electronics