Synthesis, characterization, and physical properties of two novel nonaheteroacene derivatives
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 282-285 |
Journal / Publication | Tetrahedron Letters |
Volume | 55 |
Issue number | 1 |
Online published | 16 Nov 2013 |
Publication status | Published - 1 Jan 2014 |
Externally published | Yes |
Link(s)
Abstract
Two novel nonaheteroacene derivatives: 24,27,30,33-tetra-tert-butyl-6,8,10, 17,19,21-hexaaza-1.22,4.5,11.12,15.16-tetrabenzono-nonaacene (1) and 24,27,30,33-tetra-tert-butyl-6,10,17,21-tetraaza-8,19-benzodioxin-1.22,4.5,11. 12,15.16-tetrabenzono-nonaacene (2), have been successfully synthesized through cyclocondensation reactions. The studies on UV-vis and cyclic voltammogram suggest that compound 1 has a smaller bandgap comparing to that of compound 2, indicating that oxygen atoms can destroy the conjugation in compound 2. The results are further confirmed by theoretical simulation. © 2013 Elsevier Ltd. All rights reserved.
Research Area(s)
- Cyclocondensation reaction, heteroacenes, Oligoacenes, Organic electronic materials, Synthesis
Citation Format(s)
Synthesis, characterization, and physical properties of two novel nonaheteroacene derivatives. / Li, Gang; Gao, Junkuo; Hu, Fangzhong et al.
In: Tetrahedron Letters, Vol. 55, No. 1, 01.01.2014, p. 282-285.
In: Tetrahedron Letters, Vol. 55, No. 1, 01.01.2014, p. 282-285.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review