Synthesis and structural characterization of a novel WRu2 cluster compound possessing a terminal phenylimido ligand

Ren-Chiun Lin; Yun Chi; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1039/C39920001705

Synthesis and structural characterization of a novel WRu₂ cluster compound possessing a terminal phenylimido ligand

Ren-Chiun Lin
, Yun Chi
, Shie-Ming Peng
, Gene-Hsiang Lee

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

7 Citations (Scopus)

Abstract

Cluster complex [WRu₂(C₅Me₅)(CO)₆(NPh){C(Et)C(Et)C(CF₃)CH(CF₃)}] 2, which possesses a novel terminal phenylimido ligand, has been prepared by treatment of phenylimido cluster [WRu₂(C₅Me₅)(CO)₇(µ₃-NPh)(CF₃CCHCF₃)] 1 with hex-3-yne, whereas the respective reaction with dimethyl acetylenedicarboxylate afforded [WRu₂(C₅Me₅)(CO)₆(µ₃-NPh){C(CO₂Me)C(CO₂Me)C(CF₃)CH(CF₃)}] 3 containing a regular face-bridging imido ligand; complexes 2 and 3 have been examined by single-crystal X-ray diffraction.

Original language	English
Pages (from-to)	1705-1707
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39920001705
Publication status	Published - 1992
Externally published	Yes

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@article{0d60c8bde21f466b87df581e354747b4,

title = "Synthesis and structural characterization of a novel WRu2 cluster compound possessing a terminal phenylimido ligand",

abstract = "Cluster complex [WRu2(C5Me5)(CO)6(NPh)\{C(Et)C(Et)C(CF3)CH(CF3)\}] 2, which possesses a novel terminal phenylimido ligand, has been prepared by treatment of phenylimido cluster [WRu2(C5Me5)(CO)7(µ3-NPh)(CF3CCHCF3)] 1 with hex-3-yne, whereas the respective reaction with dimethyl acetylenedicarboxylate afforded [WRu2(C5Me5)(CO)6(µ3-NPh)\{C(CO2Me)C(CO2Me)C(CF3)CH(CF3)\}] 3 containing a regular face-bridging imido ligand; complexes 2 and 3 have been examined by single-crystal X-ray diffraction.",

author = "Ren-Chiun Lin and Yun Chi and Shie-Ming Peng and Gene-Hsiang Lee",

year = "1992",

doi = "10.1039/C39920001705",

language = "English",

pages = "1705--1707",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - Synthesis and structural characterization of a novel WRu2 cluster compound possessing a terminal phenylimido ligand

AU - Lin, Ren-Chiun

AU - Chi, Yun

AU - Peng, Shie-Ming

AU - Lee, Gene-Hsiang

PY - 1992

Y1 - 1992

N2 - Cluster complex [WRu2(C5Me5)(CO)6(NPh){C(Et)C(Et)C(CF3)CH(CF3)}] 2, which possesses a novel terminal phenylimido ligand, has been prepared by treatment of phenylimido cluster [WRu2(C5Me5)(CO)7(µ3-NPh)(CF3CCHCF3)] 1 with hex-3-yne, whereas the respective reaction with dimethyl acetylenedicarboxylate afforded [WRu2(C5Me5)(CO)6(µ3-NPh){C(CO2Me)C(CO2Me)C(CF3)CH(CF3)}] 3 containing a regular face-bridging imido ligand; complexes 2 and 3 have been examined by single-crystal X-ray diffraction.

AB - Cluster complex [WRu2(C5Me5)(CO)6(NPh){C(Et)C(Et)C(CF3)CH(CF3)}] 2, which possesses a novel terminal phenylimido ligand, has been prepared by treatment of phenylimido cluster [WRu2(C5Me5)(CO)7(µ3-NPh)(CF3CCHCF3)] 1 with hex-3-yne, whereas the respective reaction with dimethyl acetylenedicarboxylate afforded [WRu2(C5Me5)(CO)6(µ3-NPh){C(CO2Me)C(CO2Me)C(CF3)CH(CF3)}] 3 containing a regular face-bridging imido ligand; complexes 2 and 3 have been examined by single-crystal X-ray diffraction.

UR - https://www.scopus.com/pages/publications/37049077202

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-37049077202&origin=recordpage

U2 - 10.1039/C39920001705

DO - 10.1039/C39920001705

M3 - RGC 21 - Publication in refereed journal

SN - 0022-4936

SP - 1705

EP - 1707

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 23

ER -