Synthesis and structural characterization of a novel WRu2 cluster compound possessing a terminal phenylimido ligand

Ren-Chiun Lin; Yun Chi; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1039/C39920001705

Author(s)

Ren-Chiun Lin
Yun Chi
Shie-Ming Peng
Gene-Hsiang Lee

Detail(s)

Original language	English
Pages (from-to)	1705-1707
Journal / Publication	Journal of the Chemical Society, Chemical Communications
Issue number	23
Publication status	Published - 1992
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1039/C39920001705 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-37049077202&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(0d60c8bd-e21f-466b-87df-581e354747b4).html

Abstract

Cluster complex [WRu₂(C₅Me₅)(CO)₆(NPh){C(Et)C(Et)C(CF₃)CH(CF₃)}] 2, which possesses a novel terminal phenylimido ligand, has been prepared by treatment of phenylimido cluster [WRu₂(C₅Me₅)(CO)₇(µ₃-NPh)(CF₃CCHCF₃)] 1 with hex-3-yne, whereas the respective reaction with dimethyl acetylenedicarboxylate afforded [WRu₂(C₅Me₅)(CO)₆(µ₃-NPh){C(CO₂Me)C(CO₂Me)C(CF₃)CH(CF₃)}] 3 containing a regular face-bridging imido ligand; complexes 2 and 3 have been examined by single-crystal X-ray diffraction.

Citation Format(s)

[ RIS ] [ BibTeX ]

Synthesis and structural characterization of a novel WRu₂ cluster compound possessing a terminal phenylimido ligand. / Lin, Ren-Chiun; Chi, Yun; Peng, Shie-Ming et al.

In: Journal of the Chemical Society, Chemical Communications, No. 23, 1992, p. 1705-1707.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Lin, R-C, Chi, Y, Peng, S-M & Lee, G-H 1992, 'Synthesis and structural characterization of a novel WRu₂ cluster compound possessing a terminal phenylimido ligand', Journal of the Chemical Society, Chemical Communications, no. 23, pp. 1705-1707. https://doi.org/10.1039/C39920001705

Lin, R-C., Chi, Y., Peng, S-M., & Lee, G-H. (1992). Synthesis and structural characterization of a novel WRu₂ cluster compound possessing a terminal phenylimido ligand. Journal of the Chemical Society, Chemical Communications, (23), 1705-1707. https://doi.org/10.1039/C39920001705

Lin R-C, Chi Y, Peng S-M, Lee G-H. Synthesis and structural characterization of a novel WRu₂ cluster compound possessing a terminal phenylimido ligand. Journal of the Chemical Society, Chemical Communications. 1992;(23):1705-1707. doi: 10.1039/C39920001705

Lin, Ren-Chiun ; Chi, Yun ; Peng, Shie-Ming et al. / Synthesis and structural characterization of a novel WRu₂ cluster compound possessing a terminal phenylimido ligand. In: Journal of the Chemical Society, Chemical Communications. 1992 ; No. 23. pp. 1705-1707.