Synthesis and photophysical properties of isocyano Ruthenium(II) quinoline-8-thiolate complexes with visible-light and near-infrared emission
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 101-107 |
| Journal / Publication | Journal of Organometallic Chemistry |
| Volume | 804 |
| Publication status | Published - 15 Feb 2016 |
Link(s)
Abstract
The reactions of [RuII(SQ)2(PPh3)2] (SQ = quinoline-8-thiolate) with different isocyanide ligands affords a series of emissive bis(quinoline-8-thiolate) ruthenium(II) complexes [RuII(SQ)2(PPh3)(CNR)] (1-6). Two isomeric forms, i.e. cis,trans (1a - 6a) and cis,cis (1b - 6b) have been separated in these reactions. With the variation on the π-accepting ability of the isocyanide ligands, the CN stretches, lowest energy absorptions and the photoluminescence can be systematically modified.
Research Area(s)
- Cyclic voltammetry, Isocyanide ligands, Photophysics, Ruthenium
Citation Format(s)
Synthesis and photophysical properties of isocyano Ruthenium(II) quinoline-8-thiolate complexes with visible-light and near-infrared emission. / Leung, Chi-Fai; Ko, Chi-Chiu.
In: Journal of Organometallic Chemistry, Vol. 804, 15.02.2016, p. 101-107.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
