Synthesis and photophysical properties of isocyano Ruthenium(II) quinoline-8-thiolate complexes with visible-light and near-infrared emission

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

Detail(s)

Original languageEnglish
Pages (from-to)101-107
Journal / PublicationJournal of Organometallic Chemistry
Volume804
Publication statusPublished - 15 Feb 2016

Abstract

The reactions of [RuII(SQ)2(PPh3)2] (SQ = quinoline-8-thiolate) with different isocyanide ligands affords a series of emissive bis(quinoline-8-thiolate) ruthenium(II) complexes [RuII(SQ)2(PPh3)(CNR)] (1-6). Two isomeric forms, i.e. cis,trans (1a - 6a) and cis,cis (1b - 6b) have been separated in these reactions. With the variation on the π-accepting ability of the isocyanide ligands, the CN stretches, lowest energy absorptions and the photoluminescence can be systematically modified.

Research Area(s)

  • Cyclic voltammetry, Isocyanide ligands, Photophysics, Ruthenium

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