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Synthesis and Nonvolatile Memory Behaviors of Dioxatetraazapentacene Derivatives

  • Gang Li
  • , Ke Zheng
  • , Chengyuan Wang
  • , Kheng Swee Leck
  • , Fangzhong Hu*
  • , Xiao Wei Sun*
  • , Qichun Zhang*
  • *Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

Two novel heteroacenes 2,3,9,10-tetra(furan-2-yl)-1,4,8,11-tetraaza-6,13- dioxapentacene (FAOP, 1) and 2,3,9,10-tetra(thiophen-2-yl)-1,4,8,11-tetraaza-6, 13-dioxapentacene (TAOP, 2) was successfully synthesized through a one-step condensation reaction, which have been fully characterized by 1H NMR (nuclear magnetic resonance), 13C NMR, FT-IR (Fourier transform infrared spectroscopy), and HRMS (high-resolution mass spectrum). The sandwich-structure memory devices have been fabricated using FAOP (1) and TAOP (2) as active layers, showing a typical bipolar resistive switching (RS) behavior in positive and negative regions. © 2013 American Chemical Society.
Original languageEnglish
Pages (from-to)6458-6462
JournalACS Applied Materials and Interfaces
Volume5
Issue number14
Online published8 Jul 2013
DOIs
Publication statusPublished - 24 Jul 2013
Externally publishedYes

Research Keywords

  • bipolar resistive switching
  • condensation reaction
  • heteroacenes
  • nonvolatile memory
  • synthesis

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